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A multi-stimuli-response metal-organic framework nanopesticide for smart weed control in agriculture SCIE
期刊论文 | 2025 , 12 (1) , 608-622 | ENVIRONMENTAL SCIENCE-NANO
WoS CC Cited Count: 11
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Abstract :

Herbicides play an important role in weed control when it comes to ensuring a high and consistent yield in agriculture, but their effectiveness is often compromised by climatic variables. Therefore, improving the climatic adaptability of pesticides is crucial to ensure sustainable agricultural development. In this study, a novel bispyribac-sodium (BIS)-zeolitic imidazolate framework-8 (ZIF-8) nanopesticide (BIS@ZIF-8) with excellent multi-stimuli-responsive properties was synthesized. The nanopesticide BIS@ZIF-8 showed a multi-stimuli response and efficient weed control. In addition, the BIS@ZIF-8 nanocomposite showed strong resistance to rainwater erosion on leaf surfaces with a BIS retention rate of 76.26% under simulated rainwater, which was 41.54% higher than the BIS retention rate of the pure herbicide. Under UV light and acidic conditions, a high concentration of BIS was released from the BIS@ZIF-8 nanocomposite, resulting in an improved weed control effect. Further analyses showed that the BIS@ZIF-8 nanocomposite retained its structural stability and adhered to the weed under rainy conditions through electrostatic interaction. Conversely, the BIS@ZIF-8 nanocomposite was depolymerized under UV light irradiation and released BIS to kill weeds. In addition, BIS@ZIF-8 showed excellent herbicidal activity under field conditions with good biosafety. This work provides a new strategy to avoid environmental and climate-induced pesticide losses and paves the way for smart weed control in agriculture. Herbicides play an important role in weed control when it comes to ensuring a high and consistent yield in agriculture, but their effectiveness is often compromised by climatic variables.

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GB/T 7714 Zhang, Dingyang , Guo, Xueping , Rao, Wenhua et al. A multi-stimuli-response metal-organic framework nanopesticide for smart weed control in agriculture [J]. | ENVIRONMENTAL SCIENCE-NANO , 2025 , 12 (1) : 608-622 .
MLA Zhang, Dingyang et al. "A multi-stimuli-response metal-organic framework nanopesticide for smart weed control in agriculture" . | ENVIRONMENTAL SCIENCE-NANO 12 . 1 (2025) : 608-622 .
APA Zhang, Dingyang , Guo, Xueping , Rao, Wenhua , Pan, Danmei , Cao, Fang , Zhai, Tianyun et al. A multi-stimuli-response metal-organic framework nanopesticide for smart weed control in agriculture . | ENVIRONMENTAL SCIENCE-NANO , 2025 , 12 (1) , 608-622 .
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The isolation, identification and efficacy of Bacillus velezensis XF-8 in tomato bacterial wilt control EI
期刊论文 | 2025 , 4 (1) , 59-69 | Advanced Agrochem
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Abstract :

Tomato bacterial wilt is an important disease caused by Ralstonia solanacearum, which is harmful to the development of tomato industry and seriously affects the yield and quality of tomato. In this study, the strain XF-8 with antagonism against R. solanacearum was isolated from soil and identified as Bacillus velezensis, and its control effect on tomato bacterial wilt was better than that of kasugamycin. The disease index of tomato plants treated with XF-8 was significantly reduced (P < 0.05) in the pot experiment, and the control effect was 74.25 %, which was higher than 45.11 % of kasugamycin treatment group. The antibacterial activity of lipopeptide extract from the fermentation supernatant of strain XF-8 was further verified, and then the inhibitory rate of the substance at the concentration of 1 mg/mL was as high as 96.20 %. The microscopic investigations indicated that the surface of R. solanacearum was wrinkled and deformed after treating with lipopeptide extract, and most of the bacteria were dead and rupture of the cell membrane, which leading to the cell death. Meanwhile, the active oxygen was produced and the lipopeptide extract could also significantly induced DNA injuries of R. solanacearum. All these results confirmed that the isolated strain B. velezensis exhibited excellent effect of preventing and controlling the tomato bacterial wilt. Moreover, XF-8 strain has high inhibitory effect on 10 types of pathogenic fungi, which shows broad-spectrum bacteriostasis. This study provides a theoretical basis and strain resources for the development and application of biopesticides, and broadened the potential biocontrol value of B. velezensis.

Keyword :

Antimicrobial mechanism Antimicrobial mechanism Bacillus velezensis Bacillus velezensis Biological control Biological control Lipopeptide extract Lipopeptide extract Tomato bacterial wilt Tomato bacterial wilt

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GB/T 7714 Xu, Jiawei , Jiang, Jiatong , Song, Zhiye et al. The isolation, identification and efficacy of Bacillus velezensis XF-8 in tomato bacterial wilt control [J]. | Advanced Agrochem , 2025 , 4 (1) : 59-69 .
MLA Xu, Jiawei et al. "The isolation, identification and efficacy of Bacillus velezensis XF-8 in tomato bacterial wilt control" . | Advanced Agrochem 4 . 1 (2025) : 59-69 .
APA Xu, Jiawei , Jiang, Jiatong , Song, Zhiye , Hong, Junhuang , Zhao, Tongchao , Wu, Kaiwen et al. The isolation, identification and efficacy of Bacillus velezensis XF-8 in tomato bacterial wilt control . | Advanced Agrochem , 2025 , 4 (1) , 59-69 .
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不同腐殖酸氧化还原产羟基自由基潜力及其对微塑料降解的影响
期刊论文 | 2025 , 54 (03) , 365-374 | 福建农林大学学报(自然科学版)
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【目的】研究不同来源的腐殖酸(humic acid, HA)在氧化还原过程中产生羟基自由基(·OH)的能力,并评估其对聚苯乙烯微塑料(polystyrene microplastics, PS-MPs)氧化降解的效果,以深入理解微生物介导的HA氧化还原循环中·OH的持续生成机制及其对污染物转化的作用。【方法】以兼性厌氧菌Bacillus thermotoleran SgZ-8(具有HA还原能力)作为模式菌株,利用牛粪堆肥HA(dung compost humic acid, dc-HA)、鸡粪堆肥HA(chicken manure compost humic acid, cc-HA)、污泥堆肥HA(sludge compost humic acid, sc-HA)建立氧化还原循环体系。采用傅里叶变换红外光谱、三维荧光光谱、X射线光电能谱等技术分析HA的结构、官能团及其产·OH能力,并测定不同HA对PS-MPs的降解效果。【结果】dc-HA、cc-HA、sc-HA在化学结构、官能团和产·OH能力方面存在显著差异。其中,dc-HA的醌基和酚基等含氧官能团更多,电子转移能力更强,产·OH能力最强。皮尔逊相关性分析表明,总酚含量、电子供给能力以及H

Keyword :

分子结构 分子结构 氧化还原循环 氧化还原循环 羟基自由基 羟基自由基 聚苯乙烯微塑料 聚苯乙烯微塑料 腐殖酸 腐殖酸

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GB/T 7714 刘钰洁 , 陈祖森 , 崔骏凯 et al. 不同腐殖酸氧化还原产羟基自由基潜力及其对微塑料降解的影响 [J]. | 福建农林大学学报(自然科学版) , 2025 , 54 (03) : 365-374 .
MLA 刘钰洁 et al. "不同腐殖酸氧化还原产羟基自由基潜力及其对微塑料降解的影响" . | 福建农林大学学报(自然科学版) 54 . 03 (2025) : 365-374 .
APA 刘钰洁 , 陈祖森 , 崔骏凯 , 陈泽伟 , 吴杰峰 , 曾秋婷 et al. 不同腐殖酸氧化还原产羟基自由基潜力及其对微塑料降解的影响 . | 福建农林大学学报(自然科学版) , 2025 , 54 (03) , 365-374 .
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Free Radicals on Aging Microplastics Regulated the Prevalence of Antibiotic Resistance Genes in the Aquatic Environment: New Insight into the Effect of Microplastics on the Spreading of Biofilm Resistomes SCIE
期刊论文 | 2025 , 59 (23) , 11735-11744 | ENVIRONMENTAL SCIENCE & TECHNOLOGY
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Abstract :

The spread of antibiotic resistance genes (ARGs) by microplastics has received a great concern in coexisting "hotspots". Despite most microplastics suffering from natural aging, little is known about the effect of aging microplastics (A-MPs) on ARGs dissemination. Here, we demonstrated significant suppression of A-MPs on ARGs dissemination in natural rivers. Although ARGs and mobile genetic elements (MGEs) were effectively enriched on A-MPs, the relative abundance of ARGs and MGEs on A-MPs as well as in receiving water decreased by approximately 21.4% to 42.3% during a period of 30 days of dissemination. Further investigation revealed that center dot OH was consistently generated on A-MPs with a maximum value of 0.2 mu mol/g. Importantly, scavenging of center dot OH significantly increased the relative abundance of ARGs and MGEs both on A-MPs and in receiving water 1.4-29.1 times, indicating the vital role of center dot OH in suppressing ARGs dissemination. Microbial analysis revealed that center dot OH inhibited the potential antibiotic-resistant bacteria in surface biofilms, such as Pseudomonas and Acinetobacter (with a decrease of 68.8% and 89.3%). These results demonstrated that center dot OH was extensively produced on A-MPs, which greatly reduced both the vertical and horizontal gene transfer of ARGs. This study provided new insights into the dissemination of ARGs through microplastics in natural systems.

Keyword :

antibioticresistance gene antibioticresistance gene antibiotic-resistantbacteria antibiotic-resistantbacteria hydroxyl radical hydroxyl radical microplastic microplastic mobile gene element mobile gene element

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GB/T 7714 Zhai, Kaipeng , Yin, Keke , Lin, Ying et al. Free Radicals on Aging Microplastics Regulated the Prevalence of Antibiotic Resistance Genes in the Aquatic Environment: New Insight into the Effect of Microplastics on the Spreading of Biofilm Resistomes [J]. | ENVIRONMENTAL SCIENCE & TECHNOLOGY , 2025 , 59 (23) : 11735-11744 .
MLA Zhai, Kaipeng et al. "Free Radicals on Aging Microplastics Regulated the Prevalence of Antibiotic Resistance Genes in the Aquatic Environment: New Insight into the Effect of Microplastics on the Spreading of Biofilm Resistomes" . | ENVIRONMENTAL SCIENCE & TECHNOLOGY 59 . 23 (2025) : 11735-11744 .
APA Zhai, Kaipeng , Yin, Keke , Lin, Ying , Chen, Shu , Bi, Yuzhang , Xing, Ruizhi et al. Free Radicals on Aging Microplastics Regulated the Prevalence of Antibiotic Resistance Genes in the Aquatic Environment: New Insight into the Effect of Microplastics on the Spreading of Biofilm Resistomes . | ENVIRONMENTAL SCIENCE & TECHNOLOGY , 2025 , 59 (23) , 11735-11744 .
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Sustainable and Biosafe Approach to Control Potato Late Blight Using Mesoporous Silica Nanoparticles SCIE
期刊论文 | 2024 , 72 (42) , 23160-23172 | JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY
WoS CC Cited Count: 1
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Abstract :

Phytophthora infestans-induced potato late blight is considered the "cancer of the potato crop." In this work, mesoporous silica nanoparticles (MSNs) with ultrahigh specific surface area (786.28 m(2)/g) were synthesized, which significantly inhibited P. infestans compared with some commercial fungicides. Moreover, MSNs inhibited the growth and reproductive of P. infestans processes, including germination, sporangia infection, and zoospore release. MSNs targeted key biological pathways and induced a stress response in the P. infestans, leading to reactive oxygen species (center dot O2-, center dot OH, and O-1(2)) production and structural damage of sporangia. Pot experiments showed that MSNs are translocated from leaves to roots of potato plants, enhancing physiological and biochemical processes, alleviating drought stress, improving resistance to pathogens, and exhibiting soil microbe-friendly. This study systematically reveals the mechanism of MSNs to weaken the reproduction process of P. infestans and confirm the safety and feasibility of MSNs as a green and sustainable fungicide.

Keyword :

biosafety biosafety mesoporous silica mesoporous silica Phytophthora infestans Phytophthora infestans ROS ROS sporangium sporangium transport transport

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GB/T 7714 Guo, Xueping , Chen, Saili , Zhang, Dingyang et al. Sustainable and Biosafe Approach to Control Potato Late Blight Using Mesoporous Silica Nanoparticles [J]. | JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY , 2024 , 72 (42) : 23160-23172 .
MLA Guo, Xueping et al. "Sustainable and Biosafe Approach to Control Potato Late Blight Using Mesoporous Silica Nanoparticles" . | JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY 72 . 42 (2024) : 23160-23172 .
APA Guo, Xueping , Chen, Saili , Zhang, Dingyang , Cao, Fang , Cui, Ziqi , Li, Huiyan et al. Sustainable and Biosafe Approach to Control Potato Late Blight Using Mesoporous Silica Nanoparticles . | JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY , 2024 , 72 (42) , 23160-23172 .
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Reduced greenhouse gas emission by reactive oxygen species during composting SCIE
期刊论文 | 2024 , 404 | BIORESOURCE TECHNOLOGY
WoS CC Cited Count: 6
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Abstract :

Reactive oxygen species (ROS) is produced in the composting, which effectively promote organic matter transformation and humification process, but the effect of ROS on greenhouse gas emissions in this process has not been understood. This study proposed and validated that ROS can effectively reduce greenhouse gas emissions in the process of composting. Compared with ordinary thermophilic composting ( o TC), thermophilic composting ( im TC) that was supplemented by iron mineral increased ROS production by 1.38 times, and significantly reduced greenhouse gas emissions by 45.12%. Microbial community analysis showed no significant difference in the abundance of microbes involved in greenhouse gas production between o TC and im TC. Further correlation analysis proved that ROS played a crucial role in influencing greenhouse gas emissions throughout the composting process, especially in the initial phase. These findings provide new strategies for managing livestock and poultry manure to mitigate climate change.

Keyword :

Carbon dioxide Carbon dioxide Hydroxyl radical Hydroxyl radical Iron mineral Iron mineral Methane Methane Nitrous oxide Nitrous oxide

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GB/T 7714 Du, Xian , Xing, Ruizhi , Lin, Ying et al. Reduced greenhouse gas emission by reactive oxygen species during composting [J]. | BIORESOURCE TECHNOLOGY , 2024 , 404 .
MLA Du, Xian et al. "Reduced greenhouse gas emission by reactive oxygen species during composting" . | BIORESOURCE TECHNOLOGY 404 (2024) .
APA Du, Xian , Xing, Ruizhi , Lin, Ying , Chen, Mingli , Chen, Zhi , Zhou, Shungui . Reduced greenhouse gas emission by reactive oxygen species during composting . | BIORESOURCE TECHNOLOGY , 2024 , 404 .
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Hybrid mechanism of microplastics degradation via biological and chemical process during composting SCIE
期刊论文 | 2024 , 408 | BIORESOURCE TECHNOLOGY
WoS CC Cited Count: 5
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Abstract :

Little is known about the synergistic effects of abiotic aging and biodegradation on microplastics (MPs) transformation in the environment. Herein, a hybrid process of MPs degradation was proposed by analyzing the effect of microorganisms and abiotic aging on aging MPs and non-aging MPs degradation during composting. The results showed that composting facilitated the oxidation and depolymerization of aging MPs, and its degradation efficiency was about three times that of non-aging MPs. Further investigation revealed that aging MPs contained higher abundance of plastic-degrading bacteria and enzyme activity than non-aging MPs. In addition, free radicals also influenced the degradation of MPs. However, path model and shielding experiments confirmed that free radicals mainly facilitated the non-aging MPs degradation (contribution was 68.8 %), while aging MPs was easily degraded by microorganisms (contribution was 72.6 %). This study provides promising strategies for scaling up plastic treatment in bioreactors through a hybrid collaboration of biological and abiotic processes.

Keyword :

Aging Aging Enzyme Enzyme Microorganisms Microorganisms Reactive oxygen species Reactive oxygen species

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GB/T 7714 Xing, Ruizhi , Zhai, Kaipeng , Du, Xian et al. Hybrid mechanism of microplastics degradation via biological and chemical process during composting [J]. | BIORESOURCE TECHNOLOGY , 2024 , 408 .
MLA Xing, Ruizhi et al. "Hybrid mechanism of microplastics degradation via biological and chemical process during composting" . | BIORESOURCE TECHNOLOGY 408 (2024) .
APA Xing, Ruizhi , Zhai, Kaipeng , Du, Xian , Chen, Xiaoyan , Chen, Zhi , Zhou, Shungui . Hybrid mechanism of microplastics degradation via biological and chemical process during composting . | BIORESOURCE TECHNOLOGY , 2024 , 408 .
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Enhanced organic matter humification by hydroxyl radical generation during electric field-assisted aerobic composting SCIE
期刊论文 | 2024 , 482 | CHEMICAL ENGINEERING JOURNAL
WoS CC Cited Count: 9
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Electric fields have been documented to promote the humification of organic matter, but the mechanism is still unclear. Herein, our proposed a new pathway for hydroxyl radical ((OH)-O-center dot) generation through electroactive bacteria enhanced electron transfer, resulting in accelerated humification of organic matter during electric field-assisted aerobic composting (EAC). The results indicated that electric field significantly enhanced the generation of reactive oxygen species (ROS) and humification of organic matter, and the anode and cathode of EAC are the main production regions of singlet oxygen (O-1(2), maximum yield 83.2-132.8 mu mol center dot kg(-1)) and (OH)-O-center dot (maximum yield 2343.4-2905.2 mu mol center dot kg(-1)), respectively. Further investigations suggested that electroactive bacteria accumulated on electrodes increased the generation of (OH)-O-center dot by promoting the transfer of electrons from electrode to oxygen, whereas quenching the generated (OH)-O-center dot significantly suppressed the process of organic matter humification. Our findings suggest that the (OH)-O-center dot production through microbe-induced electron transfer is a primary cause of organic matter humification, representing an electric field-assisted strategy overlooked biochemical process.

Keyword :

Composting Composting Electric field Electric field Electroactive bacteria Electroactive bacteria Humification Humification Hydroxyl radical Hydroxyl radical

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GB/T 7714 Xing, Ruizhi , Yin, Keke , Du, Xian et al. Enhanced organic matter humification by hydroxyl radical generation during electric field-assisted aerobic composting [J]. | CHEMICAL ENGINEERING JOURNAL , 2024 , 482 .
MLA Xing, Ruizhi et al. "Enhanced organic matter humification by hydroxyl radical generation during electric field-assisted aerobic composting" . | CHEMICAL ENGINEERING JOURNAL 482 (2024) .
APA Xing, Ruizhi , Yin, Keke , Du, Xian , Lin, Ying , Yu, Zhen , Chen, Zhi et al. Enhanced organic matter humification by hydroxyl radical generation during electric field-assisted aerobic composting . | CHEMICAL ENGINEERING JOURNAL , 2024 , 482 .
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铁掺杂氯氧化铋光芬顿催化降解水中阿特拉津的性能与机理研究
期刊论文 | 2023 , 43 (08) , 37-48 | 环境科学学报
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采用溶剂热反应制备了分级微球结构的铁掺杂氯氧化铋(Fe-BiOCl),并用于光芬顿降解阿特拉津(Atrazine,ATZ).结合多因素实验,系统地分析了以Fe-BiOCl为催化剂构建的光芬顿体系氧化降解阿特拉津的性能与机理.结果表明,当催化剂用量为0.2 g·L~(-1)、污染物浓度为20 mg·L~(-1)、H_2O_2浓度为6.4 mmol·L~(-1)时,Fe-BiOCl-2催化剂在120 min内降解阿特拉津的效率约为99.98%,且在较宽pH范围(3.04~6.02)内保持优异的降解效率.通过自由基猝灭实验和电子顺磁共振(EPR)测试发现,在光芬顿体系中羟基自由基(·OH)和超氧自由基(·O_2~-)是反应的主要活性物种.此外,通过超高效液相色谱测定降解过程中的中间产物,提出了可能的降解路径和转化机理.

Keyword :

光芬顿 光芬顿 氯氧化铋 氯氧化铋 离子掺杂 离子掺杂 阿特拉津 阿特拉津 降解 降解

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GB/T 7714 许煜航 , 蔡泳莉 , 张志强 et al. 铁掺杂氯氧化铋光芬顿催化降解水中阿特拉津的性能与机理研究 [J]. | 环境科学学报 , 2023 , 43 (08) : 37-48 .
MLA 许煜航 et al. "铁掺杂氯氧化铋光芬顿催化降解水中阿特拉津的性能与机理研究" . | 环境科学学报 43 . 08 (2023) : 37-48 .
APA 许煜航 , 蔡泳莉 , 张志强 , 何秋香 , 陈志 , 吕健 . 铁掺杂氯氧化铋光芬顿催化降解水中阿特拉津的性能与机理研究 . | 环境科学学报 , 2023 , 43 (08) , 37-48 .
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Mesoporous Silica Nanoparticles Induce Intracellular Peroxidation Damage of Phytophthora infestans: A New Type of Green Fungicide for Late Blight Control SCIE
期刊论文 | 2023 , 57 (9) , 3980-3989 | ENVIRONMENTAL SCIENCE & TECHNOLOGY
WoS CC Cited Count: 39
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Nanopesticides are considered to be a promising alternative strategy for enhancing bioactivity and delaying the development of pathogen resistance to pesticides. Here, a new type of nanosilica fungicide was proposed and demonstrated to control late blight by inducing intracellular peroxidation damage to Phytophthora infestans, the pathogen associated with potato late blight. Results indicated that the structural features of different silica nanoparticles were largely responsible for their antimicrobial activities. Mesoporous silica nanoparticles (MSNs) exhibited the highest antimicrobial activity with a 98.02% inhibition rate of P. infestans, causing oxidative stress responses and cell structure damage in P. infestans. For the first time, MSNs were found to selectively induce spontaneous excess production of intracellular reactive oxygen species in pathogenic cells, including hydroxyl radicals (center dot OH), superoxide radicals (center dot O2-), and singlet oxygen (1O2), leading to peroxidation damage in P. infestans. The effectiveness of MSNs was further tested in the pot experiments as well as leaf and tuber infection, and successful control of potato late blight was achieved with high plant compatibility and safety. This work provides new insights into the antimicrobial mechanism of nanosilica and highlights the use of nanoparticles for controlling late blight with green and highly efficient nanofungicides.

Keyword :

antimicrobial mechanism antimicrobial mechanism nanopesticides nanopesticides nanosilica nanosilica Phytophthora infestans Phytophthora infestans reactive oxygen species reactive oxygen species

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GB/T 7714 Chen, Saili , Guo, Xueping , Zhang, Bintian et al. Mesoporous Silica Nanoparticles Induce Intracellular Peroxidation Damage of Phytophthora infestans: A New Type of Green Fungicide for Late Blight Control [J]. | ENVIRONMENTAL SCIENCE & TECHNOLOGY , 2023 , 57 (9) : 3980-3989 .
MLA Chen, Saili et al. "Mesoporous Silica Nanoparticles Induce Intracellular Peroxidation Damage of Phytophthora infestans: A New Type of Green Fungicide for Late Blight Control" . | ENVIRONMENTAL SCIENCE & TECHNOLOGY 57 . 9 (2023) : 3980-3989 .
APA Chen, Saili , Guo, Xueping , Zhang, Bintian , Nie, Danyue , Rao, Wenhua , Zhang, Dingyang et al. Mesoporous Silica Nanoparticles Induce Intracellular Peroxidation Damage of Phytophthora infestans: A New Type of Green Fungicide for Late Blight Control . | ENVIRONMENTAL SCIENCE & TECHNOLOGY , 2023 , 57 (9) , 3980-3989 .
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