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Regulating the structure of cellulose-based ultrafiltration membrane to improve its performance for water purification SCIE
期刊论文 | 2023 , 192 | INDUSTRIAL CROPS AND PRODUCTS
WoS CC Cited Count: 14
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Abstract :

Cellulose and its derivatives have received much attention as green raw materials to prepare ultrafiltration membranes. However, the inferior performance (low rejection, poor anti-fouling etc.) hinders their development. To improve the preparation of cellulose based ultrafiltration membrane and its performance, in this study, we developed a facile strategy to fabricate cellulose acetate ultrafiltration membranes by adding methyl acetate (MAC, as a co-solvent) to N, N-dimethylacetamide (DMAc). The results show that the pore morphologies of the membrane can be regulated by adjusting the DMAc to MAC ratio. Under optimal conditions, the pure water flux can reach 188.0 L/m2h, with the BSA rejection ratio of 95.2 %, which is about 20 % higher than the control. Furthermore, the anti-fouling and long-term stability of ultrafiltration membranes have improved significantly. The above results support the conclusion that using a mixed solvent by adding MAC to DMAc is effective for tuning the pore structure of cellulose-based ultrafiltration membrane, hence, improving its performance for water purification.

Keyword :

Cellulose acetate Cellulose acetate Cellulose-based materials Cellulose-based materials Methyl acetate Methyl acetate Phase inversion Phase inversion Solvent mixture Solvent mixture Ultrafiltration membrane Ultrafiltration membrane

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GB/T 7714 Lin, Junkang , Fu, Chenglong , Zeng, Wenchao et al. Regulating the structure of cellulose-based ultrafiltration membrane to improve its performance for water purification [J]. | INDUSTRIAL CROPS AND PRODUCTS , 2023 , 192 .
MLA Lin, Junkang et al. "Regulating the structure of cellulose-based ultrafiltration membrane to improve its performance for water purification" . | INDUSTRIAL CROPS AND PRODUCTS 192 (2023) .
APA Lin, Junkang , Fu, Chenglong , Zeng, Wenchao , Wang, Dong , Huang, Fang , Lin, Shan et al. Regulating the structure of cellulose-based ultrafiltration membrane to improve its performance for water purification . | INDUSTRIAL CROPS AND PRODUCTS , 2023 , 192 .
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不同溶剂体系制备再生竹纤维素膜及其性能
期刊论文 | 2023 , 43 (06) , 666-672 | 森林与环境学报
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Abstract :

为寻找制备再生竹纤维素(RBC)膜合适的溶剂体系,本研究分别采用N-甲基吗啉-N-氧化物(NMMO)、1-丁基-3-甲基咪唑氯盐([BMIM]Cl)离子液体(ILs)、氢氧化钠/尿素(NaOH/urea)、二甲基乙酰胺/氯化锂(DMAc/LiCl)以及传统的铜乙二胺(CED)和二硫化碳/氢氧化钠(CS_2/NaOH)6种溶剂体系溶解竹纤维素(BC),通过温度可控平板刮膜实验装置,刮膜后利用相转换法制备RBC膜,研究膜的形貌结构、化学组成、结晶结构、热稳定性、力学性能和透光性能。结果表明,所有膜的化学组成类似于竹纤维素,结晶结构为纤维素Ⅱ型,结晶度低于竹纤维素。NMMO、ILs和NaOH/urea膜的热稳定性最高; NMMO、ILs、Na OH/urea和DMAc/Li Cl膜的拉伸强度均较高; Na OH/urea和ILs膜的透光率最高;CS_2/Na OH膜的热稳定性、拉伸强度和透光率均最低。NMMO、ILs和Na OH/urea溶剂体系在满足再生竹纤维素膜市场和环境要求方面具有巨大潜力。

Keyword :

再生竹纤维素膜 再生竹纤维素膜 力学性能 力学性能 拉伸强度 拉伸强度 溶剂 溶剂 热稳定性 热稳定性 透光率 透光率

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GB/T 7714 林珊 , 程雨桐 , 汪东 et al. 不同溶剂体系制备再生竹纤维素膜及其性能 [J]. | 森林与环境学报 , 2023 , 43 (06) : 666-672 .
MLA 林珊 et al. "不同溶剂体系制备再生竹纤维素膜及其性能" . | 森林与环境学报 43 . 06 (2023) : 666-672 .
APA 林珊 , 程雨桐 , 汪东 , 李建国 , 黄六莲 , 陈礼辉 . 不同溶剂体系制备再生竹纤维素膜及其性能 . | 森林与环境学报 , 2023 , 43 (06) , 666-672 .
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特殊浸润性膜材料的油水分离研究进展
期刊论文 | 2022 , (11) , 248-250,254 | 化学工程与装备
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Abstract :

本文简要介绍了含油废水的特点和特殊浸润性膜材料的基础理论,总结了不同特殊浸润性有机膜和无机膜材料在油水分离中的应用,并对特殊浸润性膜材料的后续研究方向做出展望。

Keyword :

油水分离 油水分离 特殊浸润 特殊浸润

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GB/T 7714 石正宝 , 陈淑卿 , 林珊 . 特殊浸润性膜材料的油水分离研究进展 [J]. | 化学工程与装备 , 2022 , (11) : 248-250,254 .
MLA 石正宝 et al. "特殊浸润性膜材料的油水分离研究进展" . | 化学工程与装备 11 (2022) : 248-250,254 .
APA 石正宝 , 陈淑卿 , 林珊 . 特殊浸润性膜材料的油水分离研究进展 . | 化学工程与装备 , 2022 , (11) , 248-250,254 .
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一种高通量纤维素正渗透膜的制备方法 incoPat ipsunlight
专利 | 2022-06-24 | CN202210721144.0
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Abstract :

本发明公开一种高通量纤维素正渗透膜的制备方法,涉及膜分离和海水淡化技术领域。本发明的制备方法包括以下步骤:1)将纤维素溶解在溶剂中,采用相转化法制备纤维素膜;2)利用纤维素酶对纤维素膜进行单面蚀刻处理获得具有非对称结构的纤维素正渗透膜。本研究发明的纤维素正渗透膜具有不对称的孔结构,呈现优异的水通量和盐截留率,且制备工艺简单,环境友好,可大规模生产。

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GB/T 7714 陈礼辉 , 袁红梅 , 李建国 et al. 一种高通量纤维素正渗透膜的制备方法 : CN202210721144.0[P]. | 2022-06-24 .
MLA 陈礼辉 et al. "一种高通量纤维素正渗透膜的制备方法" : CN202210721144.0. | 2022-06-24 .
APA 陈礼辉 , 袁红梅 , 李建国 , 林珊 . 一种高通量纤维素正渗透膜的制备方法 : CN202210721144.0. | 2022-06-24 .
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Engineered Janus cellulose membrane with the asymmetric-pore structure for the superhigh-water flux desalination SCIE
期刊论文 | 2022 , 291 | CARBOHYDRATE POLYMERS
WoS CC Cited Count: 23
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Abstract :

Membranes are the dominant material for seawater desalination and clean-water harvesting, which are commonly composed of synthetic polymers, showing low hydrophilicity and environmental hazard. Herein, we developed a low-cost, intrinsically green, superhigh-water flux Janus cellulose membrane (CEM) via a facile cellulase etching strategy. Coating cellulase on the single surface of cellulose membrane (such as top surface), triggers effective etching on its top section rather than bottom section, which architects an asymmetric-pore structure of the Janus CEM including porous top-and dense bottom-layer. Such distinction endows the Janus CEM with an unprecedented high-water flux of 135.75 LMH and a low salt-water ratio of 0.29 gmiddotL(-1) for 1 M NaCl solution, which is 17-time higher and 62-time lower than that of the pristine CEM. Our Janus CEM enables a promising participant for the advanced membrane materials toward versatile separation engineering.

Keyword :

Cellulase etching Cellulase etching Forward osmosis Forward osmosis Membrane separation Membrane separation Natural cellulose Natural cellulose

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GB/T 7714 Yuan, Hongmei , Hao, Ran , Sun, Haodong et al. Engineered Janus cellulose membrane with the asymmetric-pore structure for the superhigh-water flux desalination [J]. | CARBOHYDRATE POLYMERS , 2022 , 291 .
MLA Yuan, Hongmei et al. "Engineered Janus cellulose membrane with the asymmetric-pore structure for the superhigh-water flux desalination" . | CARBOHYDRATE POLYMERS 291 (2022) .
APA Yuan, Hongmei , Hao, Ran , Sun, Haodong , Zeng, Wenchao , Lin, Junkang , Lu, Shengchang et al. Engineered Janus cellulose membrane with the asymmetric-pore structure for the superhigh-water flux desalination . | CARBOHYDRATE POLYMERS , 2022 , 291 .
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Electrospun chitosan nanofiber constructing superhigh-water-flux forward osmosis membrane SCIE
期刊论文 | 2022 , 226 , 833-839 | INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
WoS CC Cited Count: 14
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Abstract :

Forward osmosis (FO) technology exhibits great potential in seawater desalination and wastewater treatment due to its negligible energy consumption and high antifouling, however, the weak desalination capability, especially low water flux, remains challenging. Herein, a cost-effective and high-desalination-performance chitosan (CS)-based FO membrane is developed via coupling the electrospinning CS nanofibers and interfacial-polymerized polyamide (PA). The electrospun nanofibers construct the porous and hydrophilic CS layer with the large pore-diameter of similar to 274 nm and low thickness of-10 mu m, enabling the effective transport of water molecules, specifically, a superhigh water flux of 107.53 LMH at a low salt-water ratio of 0.24 g center dot L-1. In addition, such superior desalination performance of the as-prepared FO membrane is universal for the various salt species and concentrations. Our CS nanofiber-based membrane with the high separation capability of water-salt, desirable antibacterial activity, as well as the low cost, offers a roadmap toward the sustainable membrane materials.

Keyword :

Chitosan nanofiber Chitosan nanofiber Forward osmosis Forward osmosis High-water flux High-water flux

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GB/T 7714 Zeng, Wenchao , Yu, Meiqiong , Lin, Junkang et al. Electrospun chitosan nanofiber constructing superhigh-water-flux forward osmosis membrane [J]. | INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES , 2022 , 226 : 833-839 .
MLA Zeng, Wenchao et al. "Electrospun chitosan nanofiber constructing superhigh-water-flux forward osmosis membrane" . | INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES 226 (2022) : 833-839 .
APA Zeng, Wenchao , Yu, Meiqiong , Lin, Junkang , Huang, Liulian , Li, Jianguo , Lin, Shan et al. Electrospun chitosan nanofiber constructing superhigh-water-flux forward osmosis membrane . | INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES , 2022 , 226 , 833-839 .
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再生竹纤维素中空纤维膜的制备及性能
期刊论文 | 2022 , 41 (09) , 19-25 | 中国造纸
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Abstract :

采用N-甲基吗啉-N-氧化物(NMMO)为溶剂溶解竹纤维素,通过干-湿纺法制备再生竹纤维素中空纤维膜,并采用其构建的中试膜系统对饮用水进行深度处理。结果表明,中空纤维膜的结晶结构为纤维素Ⅱ型,结晶度比竹纤维素低,化学组成与竹纤维素没有明显差异。中空纤维膜热稳定性和力学性能良好,初始热分解温度为329.8℃,拉伸强度达(62.6±6.1) MPa。饮用水处理(运行90天)后,溶解性总固体(TDS)值由574 mg/L降为154 mg/L,细菌总数由35~40 cfu/mL降为20~25 cfu/mL,出水口感好,生物安全性高。

Keyword :

NMMO NMMO 中空纤维 中空纤维 竹纤维素 竹纤维素

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GB/T 7714 林珊 , 李诗 , 汪东 et al. 再生竹纤维素中空纤维膜的制备及性能 [J]. | 中国造纸 , 2022 , 41 (09) : 19-25 .
MLA 林珊 et al. "再生竹纤维素中空纤维膜的制备及性能" . | 中国造纸 41 . 09 (2022) : 19-25 .
APA 林珊 , 李诗 , 汪东 , 袁红梅 , 黄六莲 , 陈礼辉 . 再生竹纤维素中空纤维膜的制备及性能 . | 中国造纸 , 2022 , 41 (09) , 19-25 .
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苯胺或邻苯二胺/YBCO杂化材料的性能 CSCD
期刊论文 | 2021 , 49 (04) , 167-172 | 材料工程
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Abstract :

采用高温固相法制备钇钡铜氧(YBCO),研磨后超声分散在无水乙醇中得纳米YBCO/乙醇溶胶,再分别掺入苯胺和邻苯二胺,浓缩后真空干燥得有机物/YBCO杂化材料。采用傅里叶红外光谱(FT-IR)、X射线衍射(XRD)、X射线光电子能谱(XPS)和振动样品磁强计(VSM)研究了有机物对YBCO化学组成、物相、元素价态和磁性性能的影响。结果表明,掺入0.05%~5%(质量分数,下同)范围内的苯胺、邻苯二胺不影响YBCO的红外吸收,但显著提高了其XRD衍射峰的强度。两种杂化材料中N-Y之间的相互作用比N-Ba或N-Cu强烈,N元素含量对杂化材料中YBCO的超导转变温度T_c和磁化强度M有显著影响,N元素含量超过1%,T_c明显降低,M_(min)则相应提高。

Keyword :

YBCO YBCO 杂化 杂化 苯胺 苯胺 邻苯二胺 邻苯二胺

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GB/T 7714 林珊 , 袁红梅 , 汪东 et al. 苯胺或邻苯二胺/YBCO杂化材料的性能 [J]. | 材料工程 , 2021 , 49 (04) : 167-172 .
MLA 林珊 et al. "苯胺或邻苯二胺/YBCO杂化材料的性能" . | 材料工程 49 . 04 (2021) : 167-172 .
APA 林珊 , 袁红梅 , 汪东 , 陈淑卿 , 章文贡 , 陈礼辉 . 苯胺或邻苯二胺/YBCO杂化材料的性能 . | 材料工程 , 2021 , 49 (04) , 167-172 .
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竹纤维素的制备及其功能化材料研究进展 CSCD
期刊论文 | 2021 , 6 (04) , 1-13 | 林业工程学报
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Abstract :

我国竹子资源丰富,产量大,但竹产业整体加工水平不高,传统竹产品技术含量低,市场竞争力弱。从竹纤维素利用的角度,综述了竹子纤维素的分离技术,包括预水解技术、蒸煮技术、漂白技术、漂白化学竹浆选择性去除半纤维素升级制备溶解浆技术;溶解技术,包括CS_2/NaOH溶剂体系、金属络合物溶剂体系、碱/尿素和碱/硫脲溶剂体系、NMMO/H_2O溶剂体系、离子液体溶剂体系、LiCl/DMAc溶剂体系及功能化利用技术方面的研究进展情况。根据竹纤维素具有可再生、可降解、生物相容性好、亲水性强、机械性能和耐热性能优良等特点,重点介绍了当前国内外利用竹纤维素制备高档纺织材料、过滤膜材料、生物医用材料和光电材料等方面的研究进展情况。最后,结合笔者的研究经历,就竹纤维素材料开发利用方面存在的问题及其未来研究重点和方向阐述了自己的观点,以期为探索绿色、低碳、环保的竹资源利用新技术,开发高技术含量和高附加值竹产品提供借鉴,促进我国竹产业结构升级转型和可持续发展。

Keyword :

分离 分离 功能化 功能化 溶解 溶解 竹纤维素 竹纤维素 纺织材料 纺织材料 过滤膜材料 过滤膜材料

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GB/T 7714 陈礼辉 , 曹石林 , 黄六莲 et al. 竹纤维素的制备及其功能化材料研究进展 [J]. | 林业工程学报 , 2021 , 6 (04) : 1-13 .
MLA 陈礼辉 et al. "竹纤维素的制备及其功能化材料研究进展" . | 林业工程学报 6 . 04 (2021) : 1-13 .
APA 陈礼辉 , 曹石林 , 黄六莲 , 吴慧 , 胡会超 , 刘凯 et al. 竹纤维素的制备及其功能化材料研究进展 . | 林业工程学报 , 2021 , 6 (04) , 1-13 .
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Effect of Chitosan on Membrane Formation and Processability of Bamboo Dissolving Pulp Based Ultrafiltration Membrane SCIE
期刊论文 | 2021 , 16 (3) , 4752-4768 | BIORESOURCES
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Abstract :

Bamboo dissolving pulp (BP)/chitosan (CS) blend solutions were obtained by adding different weight ratios of BP and CS particles to N-methylmorpholine-N-oxide (NMMO) solvent. The processing and membrane forming performances of the blend solutions were studied using a rotating rheometer. The BP/CS blend solutions' optimal processing temperature was 50 to 70 degrees C. When the CS weight ratio was 9.09 wt%, the viscosity of the solution decreased, which was conducive to the processing of the membrane. The BP/CS blend ultrafiltration membranes were prepared by phase transformation of the blend solutions. The results showed that the rejection rate of the BP/CS blend ultrafiltration membrane with physically added CS particles was greatly improved compared with that of the regenerated BP ultrafiltration membrane.

Keyword :

Bamboo dissolving pulp Bamboo dissolving pulp Chitosan Chitosan Rejection rate Rejection rate Rheological properties Rheological properties Ultrafiltration membrane Ultrafiltration membrane

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GB/T 7714 Yuan, Hongmei , Wu, Jianfei , Lin, Junkang et al. Effect of Chitosan on Membrane Formation and Processability of Bamboo Dissolving Pulp Based Ultrafiltration Membrane [J]. | BIORESOURCES , 2021 , 16 (3) : 4752-4768 .
MLA Yuan, Hongmei et al. "Effect of Chitosan on Membrane Formation and Processability of Bamboo Dissolving Pulp Based Ultrafiltration Membrane" . | BIORESOURCES 16 . 3 (2021) : 4752-4768 .
APA Yuan, Hongmei , Wu, Jianfei , Lin, Junkang , Huang, Liulian , Chen, Lihui , Lin, Shan . Effect of Chitosan on Membrane Formation and Processability of Bamboo Dissolving Pulp Based Ultrafiltration Membrane . | BIORESOURCES , 2021 , 16 (3) , 4752-4768 .
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