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学者姓名：邱仁辉
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Abstract ：
以环氧大豆油丙烯酸酯(AESO)和丙烯酸异冰片酯(IBOA)为原料，制备光固化生物基树脂；同时以空心玻璃微珠(HGM)为无机增强材料，制备光固化玻璃微珠/生物基树脂复合材料，并通过万能试验机、旋转流变仪、红外光谱仪、热重分析仪、扫描电子显微镜等对生物基树脂和复合材料的结构和性能进行表征。研究结果表明：生物基树脂的黏度随着IBOA用量的增加而显著降低，树脂的拉伸强度和弯曲强度随着IBOA用量的增加呈先增加后降低的趋势。当AESO和IBOA的质量比为3∶7时制备的生物基树脂A3I7的加工性能和力学性能最佳。在生物基树脂中添加HGM后，能显著提高材料的拉伸模量、弯曲模量；当HGM用量为生物基树脂总质量的2%时制备的复合材料A3I7-2%的力学性能最佳，其拉伸强度和拉伸模量可由A3I7的20.18 MPa和655.31 MPa分别提升至28.19 MPa和1 086.50 MPa。
Keyword ：
丙烯酸异冰片酯 丙烯酸异冰片酯 复合材料 复合材料 环氧大豆油丙烯酸酯 环氧大豆油丙烯酸酯 空心玻璃微珠 空心玻璃微珠
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| GB/T 7714 | 李倬航 , 陈义桢 , 黄鑫杰 et al. 光固化玻璃微珠/生物基树脂复合材料的制备与性能研究 [J]. | 生物质化学工程 , 2025 , 59 (04) : 84-90 . |
| MLA | 李倬航 et al. "光固化玻璃微珠/生物基树脂复合材料的制备与性能研究" . | 生物质化学工程 59 . 04 (2025) : 84-90 . |
| APA | 李倬航 , 陈义桢 , 黄鑫杰 , 叶世俊 , 林良金 , 邱仁辉 et al. 光固化玻璃微珠/生物基树脂复合材料的制备与性能研究 . | 生物质化学工程 , 2025 , 59 (04) , 84-90 . |
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本发明公开了纳米硅溶胶增强碳酸钠激发矿渣再生砂浆及其制备方法，本方案砂浆成分中，采用碳酸钠作为激发剂，其具有原材料广泛易得、腐蚀性和收缩开裂小、后期强度高、能耗和成本低等优点；而组分中的纳米硅溶胶可以很好地弥补由碳酸钠激发矿渣所造成的凝结速度慢和早期强度低的不足，同时能强化再生细骨料的界面过渡区，显著提高砂浆的强度和粘结性能；矿渣和再生细骨料均为固体废弃物，可提高固废利用率并减少垃圾填埋和土地占用，有利于环境治理保护。本发明一方面可显著减少二氧化碳等温室气体的排放；另一方面可促进固废利用，缓解天然砂石短缺，取得显著的经济、环境和社会效益，具有广阔的推广应用前景。
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| GB/T 7714 | 郑小燕 , 刘煌海 , 邱仁辉 et al. 纳米硅溶胶增强碳酸钠激发矿渣再生砂浆及其制备方法 : CN202311531601.0[P]. | 2023-11-16 . |
| MLA | 郑小燕 et al. "纳米硅溶胶增强碳酸钠激发矿渣再生砂浆及其制备方法" : CN202311531601.0. | 2023-11-16 . |
| APA | 郑小燕 , 刘煌海 , 邱仁辉 , 陈宗燕 , 罗刚 , 虞元茂 et al. 纳米硅溶胶增强碳酸钠激发矿渣再生砂浆及其制备方法 : CN202311531601.0. | 2023-11-16 . |
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本发明公开了一种可光修复的碳点增强生物基弹性体，属于生物基纳米材料和生物基弹性体领域。本发明利用以棕榈酸为原料，通过水热法制备的生物基碳点为增强体，通过将其与棕榈油脂肪酸丙烯酰胺乙酯配合，并加入丙烯酸羟乙酯和丙烯酰氧乙基三甲基氯化铵为共聚单体，在光引发剂的作用下通过光固化技术制得所述生物基弹性体。本发明原料来源于生物基材料，环境友好；生物基碳点的加入显著提高了弹性体的拉伸断裂伸长率、断裂韧性和拉伸强度；且碳点的光热效应可使得弹性体具有优异的光修复性能。
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| GB/T 7714 | 刘文地 , 林竞鸿 , 李影 et al. 一种可光修复的碳点增强生物基弹性体 : CN202411876656.X[P]. | 2024-12-19 . |
| MLA | 刘文地 et al. "一种可光修复的碳点增强生物基弹性体" : CN202411876656.X. | 2024-12-19 . |
| APA | 刘文地 , 林竞鸿 , 李影 , 邱仁辉 , 费铭恩 . 一种可光修复的碳点增强生物基弹性体 : CN202411876656.X. | 2024-12-19 . |
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Plant oil-based waterborne polyurethanes (WPU) take advantage over traditional solvent-based polyurethanes by using sustainable raw material sources and avoiding VOC emissions. However, the preparation of plant oil-based WPU usually requires long drying times and high energy consumption. Developing plant oil-based WPU with high solid content and low viscosity emerges as a promising solution for these challenges. In this study, a palm oil-based monomer, POEA-MA, with unevenly distributed carboxyl groups on the side chains was synthesized through thiol-ene click chemistry. Utilizing this unique molecular structure, we successfully developed a palm oil-based WPU with bimodal particle distribution, achieving both high solid content (51%) and low viscosity (277.3 mPa center dot s). The introduction of 1,6-naphthalenediol as a rigid diol enhanced the main chain rigidity and increased the hydrogen bond content of the system, allowing the WPU films with tunable tensile properties (tensile strength 1.3-13.9 MPa, elongation at break 122-384%) and hardness (4B-4H). The prepared WPU films demonstrated commendable performance in coating applications, including strong corrosion resistance with a corrosion inhibition rate of 99.56%, outstanding adhesion (5B), high flexibility (Phi 1 mm), impact resistance (1 m), and good solvent resistance.
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| GB/T 7714 | Geng, Shimin , Hu, Yongtao , Hong, Xinwen et al. Palm oil-based waterborne polyurethanes: Achieving high-solid and low-viscosity through bimodal particle design [J]. | CHEMICAL ENGINEERING JOURNAL , 2025 , 519 . |
| MLA | Geng, Shimin et al. "Palm oil-based waterborne polyurethanes: Achieving high-solid and low-viscosity through bimodal particle design" . | CHEMICAL ENGINEERING JOURNAL 519 (2025) . |
| APA | Geng, Shimin , Hu, Yongtao , Hong, Xinwen , Chen, Tingting , Fei, Mingen , Wu, Shuyi et al. Palm oil-based waterborne polyurethanes: Achieving high-solid and low-viscosity through bimodal particle design . | CHEMICAL ENGINEERING JOURNAL , 2025 , 519 . |
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A sustainable and flame-retardant composite facing layers was developed using recycled polyethylene terephthalate (rPET) fiber-mats and renewable soybean oil-based resins. The rPET fiber-mats were surface-treated with a finishing agent composed of paraformaldehyde and dicyandiamide. This finishing agent can interact with the fiber surface both physically and chemically, aiming to enhance composite interfacial adhesion. A flame-retardant soybean oil-based resin, from epoxidized soybean oil, tannic acid, and 2-hydroxyethyl methacrylate phosphate, was used as the matrix. The composites exhibited a limited oxygen index of 28.68 %, with reduced heat release and flue gas emission during combustion. The treatment of rPET fibers contributed to improvements in thermal and mechanical properties of the composites. When used as outer layers, this composite also enhanced both flame retardancy and mechanical performance of the paper honeycomb panels. This study introduces an innovative approach to replacing traditional nonrenewable and flammable facing layers in honeycomb panels with recycled and renewable materials.
Keyword ：
Fiber-reinforced composites Fiber-reinforced composites Flame-retardancy Flame-retardancy Honeycomb panel Honeycomb panel Polyethylene terephthalate Polyethylene terephthalate Renewable resources Renewable resources
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| GB/T 7714 | Chen, Yizhen , Zhang, Liyuan , Qiu, Renhui et al. Flame-retardant composites from recycled PET fibers and soybean oil-based resins: A sustainable solution for honeycomb panel skins [J]. | COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING , 2025 , 199 . |
| MLA | Chen, Yizhen et al. "Flame-retardant composites from recycled PET fibers and soybean oil-based resins: A sustainable solution for honeycomb panel skins" . | COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING 199 (2025) . |
| APA | Chen, Yizhen , Zhang, Liyuan , Qiu, Renhui , Chen, Tingting , Fei, Mingen , Liu, Wendi . Flame-retardant composites from recycled PET fibers and soybean oil-based resins: A sustainable solution for honeycomb panel skins . | COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING , 2025 , 199 . |
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本发明公开了一种改性矿渣纤维增强水泥砂浆及其制备方法。本发明采用改性矿渣纤维作为增强体，具有合理利用固体废弃物，能耗低、成本低、绿色环保，以及砂浆试件力学性能高、收缩开裂小等优势。采用纳米硅溶胶改性矿渣纤维可以更好地提高矿渣纤维在水泥材料中的耐久性，同时能够使纤维表面水化产物分布更加均匀、细密，有利于强化纤维与基体材料的界面过渡区，从而显著提高砂浆的强度；所使用的矿渣纤维是以高炉矿渣和粉煤灰为原料，通过喷吹或离心甩丝工艺制备而成的纤维状材料，可提高固废利用率，有利于环境治理与保护。本发明的实施一方面探索了矿渣纤维在水泥基体材料中的实际应用；另一方面也可促进固废利用。
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| GB/T 7714 | 邱仁辉 , 凌琨淇 , 刘文地 et al. 一种改性矿渣纤维增强水泥砂浆及其制备方法 : CN202510618234.0[P]. | 2025-05-14 . |
| MLA | 邱仁辉 et al. "一种改性矿渣纤维增强水泥砂浆及其制备方法" : CN202510618234.0. | 2025-05-14 . |
| APA | 邱仁辉 , 凌琨淇 , 刘文地 , 郑小燕 , 费铭恩 . 一种改性矿渣纤维增强水泥砂浆及其制备方法 : CN202510618234.0. | 2025-05-14 . |
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本发明公开了基于模拟和深度学习的刨花板力学性能预测分析方法，本方案利用有限元模拟和理论构建单位厚度刨花板各向异性小片层拼接结构的等效单层板力学模型，获得刨花板几何形貌和应力应变分布数据集；进而构建刨花板垂直方向堆叠结构的等效层合板力学模型，获得刨花板结构参数和力学性能数据集。利用数据集分别训练人工智能模型，基于刨花板加工过程中获得的刨花片实时铺装结构，利用训练后的人工智能模型，实现刨花板力学性能的快速智能预测及品质控制。本方案具有操作简易，通用性强，检测效率高，处理精度高，技术成本低，品质控制性强等优点；其对刨花板小片层铺装结构的构效关系分析、力学性能预测、生产在线品控等领域具有重要意义。
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| GB/T 7714 | 吴淑一 , 杨正周 , 邱仁辉 et al. 基于模拟和深度学习的刨花板力学性能预测分析方法 : CN202411959007.6[P]. | 2024-12-30 . |
| MLA | 吴淑一 et al. "基于模拟和深度学习的刨花板力学性能预测分析方法" : CN202411959007.6. | 2024-12-30 . |
| APA | 吴淑一 , 杨正周 , 邱仁辉 , 胡磊 , 杨艳 , 刘文地 . 基于模拟和深度学习的刨花板力学性能预测分析方法 : CN202411959007.6. | 2024-12-30 . |
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Traditional polyurethane hot-melt adhesives often fall short in achieving high bonding strength and recyclability, and their dependence on non-renewable resources poses a significant hurdle for sustainable development. In this study, a palm oil-based diethanolamide (POEA) containing a long aliphatic chain was synthesized to develop comb thermoplastic polyurethane hot-melt adhesives (POPUs) with high biobased content, superior adhesion strength, and reusability. The microphase separation structure of POPUs was manipulated through the incorporation of dangling fatty acid chains and hydrogen bonds, resulting in the adhesives with excellent mechanical properties, with an optimum tensile strength of 5.37 MPa and an elongation at break of 282 %. As a hot-melt adhesive, it achieved a maximum lap-shear strength of 7.34 MPa on steel and maintained an average strength of 95 % of its initial value across multiple bonding cycles. Moreover, its lap-shear strengths with wood and glass remained at 6.57 MPa and 3.57 MPa respectively, fully meeting the requirements for interior decoration. Additionally, it was unexpectedly discovered that the adhesives possessed fluorescence characteristics, which can be applied in fields such as cultural relic restoration and anti-counterfeiting.
Keyword ：
Adhesive strength Adhesive strength Biobased polyurethane adhesive Biobased polyurethane adhesive Fluorescence Fluorescence Palm oil Palm oil
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| GB/T 7714 | Huang, Zhen , Geng, Shimin , Chen, Yizhen et al. Biobased comb polyurethane hot-melt adhesives consisting of dangling fatty acid chains and H-bonds for tailoring bonding strength [J]. | EUROPEAN POLYMER JOURNAL , 2025 , 229 . |
| MLA | Huang, Zhen et al. "Biobased comb polyurethane hot-melt adhesives consisting of dangling fatty acid chains and H-bonds for tailoring bonding strength" . | EUROPEAN POLYMER JOURNAL 229 (2025) . |
| APA | Huang, Zhen , Geng, Shimin , Chen, Yizhen , Li, Ying , Fei, Mingen , Qiu, Renhui et al. Biobased comb polyurethane hot-melt adhesives consisting of dangling fatty acid chains and H-bonds for tailoring bonding strength . | EUROPEAN POLYMER JOURNAL , 2025 , 229 . |
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Alkali-activated slag mortars with recycled fine aggregate (AASRMs) have attracted high concern due to their promising properties, low carbon emissions, and solid waste utilization. However, high shrinkage made the AASRMs susceptible to cracking, limiting their application in construction industry. This study intends to use green bamboo cellulose nanofibers (CNFs) as reinforcement to overcome the problem. Two CNFs surface modifications including nano-SiO2 coating and KH590 silane were adopted to improve the dispersibility of CNFs and their compatibility with AASRM matrix. Fourier transform infrared spectroscopy, thermal gravimetric analysis, Zeta potential, and scanning electron microscopy were adopted to characterize the CNF modification. The results showed that adding CNFs evidently improved the mechanical strengths, and reduced the chemical and dry shrinkages of AASRMs. CNF to modifications improved their dispersibility within the matrix, strengthened the fiber/matrix interface bonding, and refined the pore structure of the mortars, enhancing the overall performance of AASRMs. Particularly, the incorporation of 0.3 wt% nano-SiO2- and KH590-modified CNFs into AASRMs enhanced the 28-day flexural strength by 15.5 % and 18.3 %, respectively, compared to the control without CNFs. Moreover, these modifications significantly reduced the 14-day dry shrinkage by 49.9 % and 37.1 %, with nano-SiO2 proving more effective than KH590 in mitigating dry shrinkage. This study offers an effective and green strategy for enhancing the performance of AASRMs by using renewable materials, being beneficial for their large-scale application as sustainable building materials.
Keyword ：
Alkali-activated slag recycled mortar Alkali-activated slag recycled mortar Bamboo cellulose nanofibers Bamboo cellulose nanofibers Interface enhancement Interface enhancement Shrinkage performance Shrinkage performance Surface modification Surface modification
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| GB/T 7714 | Lu, Hongye , Wang, Yulin , Zhang, Peng et al. Nano-SiO2 coating and silane modified bamboo cellulose nanofibers for alkali-activated slag mortar with recycled aggregate: Performance enhancement and mechanism [J]. | CONSTRUCTION AND BUILDING MATERIALS , 2025 , 458 . |
| MLA | Lu, Hongye et al. "Nano-SiO2 coating and silane modified bamboo cellulose nanofibers for alkali-activated slag mortar with recycled aggregate: Performance enhancement and mechanism" . | CONSTRUCTION AND BUILDING MATERIALS 458 (2025) . |
| APA | Lu, Hongye , Wang, Yulin , Zhang, Peng , Lin, Qingpeng , Chen, Zongyan , Qiu, Renhui et al. Nano-SiO2 coating and silane modified bamboo cellulose nanofibers for alkali-activated slag mortar with recycled aggregate: Performance enhancement and mechanism . | CONSTRUCTION AND BUILDING MATERIALS , 2025 , 458 . |
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The development of fiber reinforced asphalt mixture alleviates pavement distress and damage, extending the service life of asphalt pavements; however, the weak fiber/asphalt interface adhesion may limit its wider adoption in practical scenarios. We developed a fiber reinforced asphalt mixture utilizing slag fibers derived from solid waste as a novel solution for waste management. The surface of the slag fibers was modified with silane coupling agents to enhance the interface adhesion between the fiber and the asphalt matrix. Both molecular dynamics simulation and experimental results confirmed the effectiveness of the surface modification, showing increased interfacial compatibility and adhesion. The optimized fiber contents for asphalt mixtures were determined through Marshall tests, indicating that 0.3 wt% of modified short slag fiber or 0.4 wt% of modified long slag fiber yielded the most favorable results. The road performance of asphalt mixture was significantly improved, with increases of > 11.8 % in indirect tensile strength, > 22.5 % in dynamic stability, and > 10.7 % in flexural tensile strength at low temperatures. A great improvement in the stability of the asphalt mixture was achieved under varying temperatures. The robust fiber/asphalt interface allows stress to be easily transferred and enables the asphalt to be tightly absorbed by the fibers, stabilizing the asphalt mixture. After 10 months of service, field evaluations showed minimal deflection and few defects, confirming the practicality and durability of the modified slag fiber reinforced asphalt mixtures. This study offers a feasible and effective way to enhance asphalt pavement performance while addressing solid waste management issues.
Keyword ：
Fiber reinforced asphalt Fiber reinforced asphalt Molecular dynamics simulation Molecular dynamics simulation On-site paving On-site paving Road Performance Road Performance Slag fiber Slag fiber
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| GB/T 7714 | Fei, Mingen , Cai, Qingbing , Wu, Weijian et al. Surface modified slag fiber reinforced asphalt mixture: Enhancement of pavement performance and field validation [J]. | CASE STUDIES IN CONSTRUCTION MATERIALS , 2025 , 22 . |
| MLA | Fei, Mingen et al. "Surface modified slag fiber reinforced asphalt mixture: Enhancement of pavement performance and field validation" . | CASE STUDIES IN CONSTRUCTION MATERIALS 22 (2025) . |
| APA | Fei, Mingen , Cai, Qingbing , Wu, Weijian , Yan, Xiaoqian , Zhao, Huilong , Yu, Kunming et al. Surface modified slag fiber reinforced asphalt mixture: Enhancement of pavement performance and field validation . | CASE STUDIES IN CONSTRUCTION MATERIALS , 2025 , 22 . |
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