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学者姓名：陈奶荣
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本发明公开了一种基于仿生矿化有机‑无机杂化的水下胶黏剂及其制备方法和应用，属于胶黏剂技术领域。所述胶黏剂包括不饱和油脂、无机化合物及氧化剂。本发明的胶黏剂对于各种基材均具有高的胶接强度，并且在各种溶液环境中保持较高强度。本发明的胶黏剂可用于水下结构的胶接、维修和加固。本发明选用的原料价廉易得，制备工艺简单，无需复杂合成，适合工业规模化生产，在胶黏剂技术领域具有深远的应用前景。
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| GB/T 7714 | 李枫 , 李梦涵 , 陈奶荣 et al. 一种基于仿生矿化有机-无机杂化的水下胶黏剂及其制备方法和应用 : CN202510389993.4[P]. | 2025-03-31 . |
| MLA | 李枫 et al. "一种基于仿生矿化有机-无机杂化的水下胶黏剂及其制备方法和应用" : CN202510389993.4. | 2025-03-31 . |
| APA | 李枫 , 李梦涵 , 陈奶荣 , 朱志强 , 黄友辉 , 张嘉怡 . 一种基于仿生矿化有机-无机杂化的水下胶黏剂及其制备方法和应用 : CN202510389993.4. | 2025-03-31 . |
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本发明提供了一种全组分利用虾蟹壳制备木材胶黏剂的方法，以废弃虾蟹壳为原料，经过球磨、表面氨基化等步骤，解聚组分，再固化交联，制备成胶黏剂；该方法不仅充分利用渔业加工废弃物，还提高了胶黏剂的耐水粘接性能。该胶黏剂可用于生产刨花板、纤维板、胶合板等人造板，制备的人造板无游离甲醛释放，具有天然的抗菌防霉效果，能够广泛用于家具或装修行业，具有广阔的应用前景。
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| GB/T 7714 | 陈奶荣 , 朱志强 , 李枫 . 一种全组分利用虾蟹壳制备木材胶黏剂的方法 : CN202410295577.3[P]. | 2024-03-15 . |
| MLA | 陈奶荣 et al. "一种全组分利用虾蟹壳制备木材胶黏剂的方法" : CN202410295577.3. | 2024-03-15 . |
| APA | 陈奶荣 , 朱志强 , 李枫 . 一种全组分利用虾蟹壳制备木材胶黏剂的方法 : CN202410295577.3. | 2024-03-15 . |
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本发明提供了一种含微凝胶结构的高性能无醛茶籽粕木材胶黏剂及其制备方法。以机械力将茶籽粉碎至粉状，室温下，使用正己烷去除茶籽粕的油脂，进一步粉碎至大于200目，降低其粒径，暴露活性官能团（如氨基、羧基、羟基）。茶籽粕、改性剂和天然多酚在微波控温作用下，发生非共价自组装聚集行为，形成微凝胶，降低体系黏度；后续使用时，在热压过程中，微凝胶破碎，改性剂与茶籽粕中的活性基团反应形成刚性共价网络，含有儿茶酚基团天然多酚与改性剂和茶籽粕形成柔性非共价网络，刚柔并济的交联网络赋予茶籽粕胶黏剂强大的耐水能力，应用前景良好。
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| GB/T 7714 | 陈奶荣 , 吴梓楷 , 黄友辉 et al. 一种含微凝胶结构的高性能无醛茶籽粕木材胶黏剂及其制备方法 : CN202510142848.6[P]. | 2025-02-10 . |
| MLA | 陈奶荣 et al. "一种含微凝胶结构的高性能无醛茶籽粕木材胶黏剂及其制备方法" : CN202510142848.6. | 2025-02-10 . |
| APA | 陈奶荣 , 吴梓楷 , 黄友辉 , 李枫 . 一种含微凝胶结构的高性能无醛茶籽粕木材胶黏剂及其制备方法 : CN202510142848.6. | 2025-02-10 . |
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本发明提供了一种解聚虾蟹壳改性的低游离甲醛氨基树脂胶黏剂及其制备方法。以机械力将甲壳类动物外壳粉碎成粉状，降低其粒径，形成微米尺度虾蟹壳微粒，提高比表面积。分别以酸和碱依次溶解虾蟹壳粉中的部分碳酸钙和蛋白质，虾蟹壳微粒表面将暴露出大量甲壳素。以碱液溶解蛋白质，也会引发甲壳素脱乙酰基，产生‑NH2等官能团。这样，微粒表面将生成大量含氨基的壳聚糖。氨基与脲醛树脂中的游离甲醛/羟甲基反应，既对树脂起增强作用，又降低了游离甲醛含量。
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| GB/T 7714 | 陈奶荣 , 朱志强 , 李枫 . 一种解聚虾蟹壳改性的低游离甲醛氨基树脂胶黏剂及其制备方法 : CN202410295620.6[P]. | 2024-03-15 . |
| MLA | 陈奶荣 et al. "一种解聚虾蟹壳改性的低游离甲醛氨基树脂胶黏剂及其制备方法" : CN202410295620.6. | 2024-03-15 . |
| APA | 陈奶荣 , 朱志强 , 李枫 . 一种解聚虾蟹壳改性的低游离甲醛氨基树脂胶黏剂及其制备方法 : CN202410295620.6. | 2024-03-15 . |
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本发明公开了一种具有自愈性的聚丁二烯丙烯酸酯光敏树脂组合物及其在405nm光固化3D打印中的应用。所述的组合物由如下质量份的原料制备而成:1~60份具有自愈性的聚丁二烯丙烯酸酯、1~40份活性稀释剂、1~5份光引发剂。制备的光敏树脂组合物可应用于405nm光固化3D打印，具有打印复杂结构的能力，其制备方法简便，力学性能良好，自修复和回收方法简单，且修复后能保持良好的力学性能，对于3D打印在一些需求较高的应用领域具有重要的意义。
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| GB/T 7714 | 卓东贤 , 宁航 , 陈奶荣 et al. 具有自愈性的聚丁二烯丙烯酸酯光敏树脂组合物及其在405nm光固化3D打印中的应用 : CN202411242541.5[P]. | 2024-09-05 . |
| MLA | 卓东贤 et al. "具有自愈性的聚丁二烯丙烯酸酯光敏树脂组合物及其在405nm光固化3D打印中的应用" : CN202411242541.5. | 2024-09-05 . |
| APA | 卓东贤 , 宁航 , 陈奶荣 , 陈少云 , 瞿波 , 郑燕玉 et al. 具有自愈性的聚丁二烯丙烯酸酯光敏树脂组合物及其在405nm光固化3D打印中的应用 : CN202411242541.5. | 2024-09-05 . |
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Composite materials, particularly wood-based panels, are frequently subjected to the harsh conditions of their service environments, leading to adhesive layer degradation and a consequent reduction in mechanical integrity and service life. The integration of self-repairing capabilities into these composites via microencapsulation presents a promising strategy to mitigate such degradation. Here, we developed a unique soy-protein-based adhesive with self-repairing capability by leveraging Pickering emulsion templated microcapsules. The microcapsules possess a melamine formaldehyde resin/polyurea shell and an isophorone diisocyanate (IPDI) core, which can exhibit excellent stability to maintain a 60.6 % encapsulation efficiency even after storing for 30 days. By incorporating with the microcapsules, the adhesive is demonstrated to display pressure-sensitive behavior. Such behavior enables the release of IPDI through mechanical stress and thus crosslinks with soy protein for crack repairing. The feature of wide particle size distribution of the microcapsules contributes to enhance both adhesion strength (reaching to 0.82 MPa to wood) and self-repairing rate (up to 93.5 %) of the wood-based composite. This innovative approach offers a practical and efficient method for endowing wood-based panels with autonomous healing capabilities, paving the way for the development of advanced self-repairing biomass composites. © 2025
Keyword ：
Adhesives Adhesives Biomass Biomass Crosslinking Crosslinking Emulsification Emulsification Emulsions Emulsions Energy efficiency Energy efficiency Hydroelasticity Hydroelasticity Microencapsulation Microencapsulation Ostwald ripening Ostwald ripening Wood products Wood products
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| GB/T 7714 | Huang, Youhui , Tu, Yijing , Zhu, Zhiqiang et al. Self-repairing wood-based composites enabled by pressure-sensitive soy-protein-based adhesive containing microcapsules [J]. | Results in Engineering , 2025 , 25 . |
| MLA | Huang, Youhui et al. "Self-repairing wood-based composites enabled by pressure-sensitive soy-protein-based adhesive containing microcapsules" . | Results in Engineering 25 (2025) . |
| APA | Huang, Youhui , Tu, Yijing , Zhu, Zhiqiang , Zhang, Jiayi , Li, Feng , Chen, Nairong . Self-repairing wood-based composites enabled by pressure-sensitive soy-protein-based adhesive containing microcapsules . | Results in Engineering , 2025 , 25 . |
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Nature excels in synthesizing advanced protein adhesives under mild condition, utilizing enzyme catalysis to achieve controllable and adjustable cold-set adhesion. To emulate this natural prowess in synthetic protein adhesives (SPAs), which are often hindered by low reactivity, weak controllability, and poor selectivity, we developed a biomimetic-enzyme-catalysis strategy to successfully construct SPAs with cold-set adhesion function via a facile one-pot method. By employing magnesium oxide (MgO) as a catalyst, the resultant adhesive demonstrated enhanced and versatile adhesion capabilities (1.67/0.98 MPa to wood for dry/wet condition, respectively), with controllable and adjustable adhesion by tailoring crosslinked and catalytic sites. Moreover, this design was applicable to various types of crosslinkers and proteins to create more robust cold-set SPAs. The investigation of the catalysis mechanism has revealed that MgO selectively and controllably interacts with adhesive molecules, effectively lowering the energy barrier necessary for successful molecular crosslinks at room temperature. Together with its demonstrated potential in large-scale and long-term applications, our strategy provides a viable pathway for the eco-friendly and scalable production of high-quality cold-set SPAs that rival natural protein adhesives.
Keyword ：
Biomimetic catalysis Biomimetic catalysis Cold-set adhesion Cold-set adhesion Controllable catalysis Controllable catalysis Metal oxides Metal oxides Protein adhesive Protein adhesive
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| GB/T 7714 | Zhu, Zhiqiang , Chen, Nairong , Huang, Youhui et al. Biomimetic catalysis design enables controllable and adjustable cold-set protein adhesive [J]. | CHEMICAL ENGINEERING JOURNAL , 2025 , 520 . |
| MLA | Zhu, Zhiqiang et al. "Biomimetic catalysis design enables controllable and adjustable cold-set protein adhesive" . | CHEMICAL ENGINEERING JOURNAL 520 (2025) . |
| APA | Zhu, Zhiqiang , Chen, Nairong , Huang, Youhui , Chen, Lihui , Shuai, Li , Li, Feng . Biomimetic catalysis design enables controllable and adjustable cold-set protein adhesive . | CHEMICAL ENGINEERING JOURNAL , 2025 , 520 . |
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High-performance resins that can withstand temperature changes are required to expand the application potential of additive manufacturing (3D printing) in response to increasing demand from various fields. In this study, a novel 3D-printing polybutadiene polyurethane acrylate photosensitive resin named HTPBMA was prepared by mixing hydroxyl-terminated polybutadiene (HTPB) as the base material with other active diluent monomers and photoinitiators, including hydroxypropyl methacrylate (HPMA). The resulting resins exhibited good rheological properties and rapid photocuring ability, depending on the type and proportion of diluent monomer. In particular, the tensile strength and elongation at break of the sample with a 65:35 HTPBMA:HPMA ratio at-25 degrees C were 32.9 MPa and 246.1%, respectively, being 2.13 and 1.58 times the values at room temperature, respectively. These results indicate that HTPBMA exhibits excellent low-temperature performance and physical properties. The enhancement mechanism can likely be attributed to introducing of a flexible carbon chain as well as increased cross-linking density (upsilon e). These advantages suggest that the novel photosensitive resin designed and prepared in this study can be used for photocuring 3D printing and maintain excellent performance under extreme climatic conditions. Thus, the proposed HTPBMA has broad application prospects in aerospace and materials science, especially in shoe materials and tires.
Keyword ：
Hydroxyl-terminated polyurethane Hydroxyl-terminated polyurethane Mechanical properties Mechanical properties Temperature resistance Temperature resistance Three-dimensional printing Three-dimensional printing
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| GB/T 7714 | Ning, Hang , Chen, Shaoyun , Liu, Yan'e et al. Polybutadiene polyurethane acrylate photosensitive resin and its application in 3D printing [J]. | JOURNAL OF SCIENCE-ADVANCED MATERIALS AND DEVICES , 2025 , 10 (1) . |
| MLA | Ning, Hang et al. "Polybutadiene polyurethane acrylate photosensitive resin and its application in 3D printing" . | JOURNAL OF SCIENCE-ADVANCED MATERIALS AND DEVICES 10 . 1 (2025) . |
| APA | Ning, Hang , Chen, Shaoyun , Liu, Yan'e , Qu, Bo , Zheng, Yanyu , Liu, Xiaoying et al. Polybutadiene polyurethane acrylate photosensitive resin and its application in 3D printing . | JOURNAL OF SCIENCE-ADVANCED MATERIALS AND DEVICES , 2025 , 10 (1) . |
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Biomass-derived materials have garnered significant attention as sustainable anode candidates for lithium-ion batteries (LIBs) owing to their abundance, low cost, and environmental benefits. Among these, Cenchrus fungigraminus (JUJUNCAO) stands out due to its rapid growth, high yield, and exceptional environmental adaptability, making it a promising precursor for carbon-based electrodes. In this study, activated carbon was synthesized from JUJUNCAO through a two-step process involving carbonization and KOH activation. By systematically varying the activation temperature and the biochar/KOH weight ratio, we precisely controlled key properties such as the degree of graphitization, porosity, chemical composition, and electrochemical performance. The optimized activated carbon exhibited a high specific surface area of 1055 m2 g- 1 and delivered a reversible specific capacity of 393 mAh g- 1 after 650 charge/discharge cycles at a current density of 0.1 A g- 1. This superior electrochemical performance is attributed to the hierarchical porous structure and heteroatom doping, which synergistically enhance lithium-ion diffusion and electron transport. These findings not only underscore the potential of JUJUNCAO as a sustainable, high-performance anode material for LIBs but also pave the way for the high-value utilization of biomass in green energy storage technologies.
Keyword ：
Activated carbon Activated carbon Carbonization temperature Carbonization temperature JUJUNCAO (Cenchrus fungigraminus) JUJUNCAO (Cenchrus fungigraminus) KOH activation KOH activation Lithium-ion battery Lithium-ion battery
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| GB/T 7714 | Guo, Zhiyun , Cheng, Tong , Zheng, Weicheng et al. Sustainable anode materials from Cenchrus fungigraminus biomass for advanced lithium-ion batteries [J]. | JOURNAL OF ELECTROANALYTICAL CHEMISTRY , 2025 , 985 . |
| MLA | Guo, Zhiyun et al. "Sustainable anode materials from Cenchrus fungigraminus biomass for advanced lithium-ion batteries" . | JOURNAL OF ELECTROANALYTICAL CHEMISTRY 985 (2025) . |
| APA | Guo, Zhiyun , Cheng, Tong , Zheng, Weicheng , Zeng, Qinzhi , Chen, Nairong , Zhao, Weigang et al. Sustainable anode materials from Cenchrus fungigraminus biomass for advanced lithium-ion batteries . | JOURNAL OF ELECTROANALYTICAL CHEMISTRY , 2025 , 985 . |
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Introducing dynamics into bio-based adhesives shows many advantages on rendering mechanics and functions. However, the efficient employment of dynamic chemistry in achieving robust, stable, and reusable bio-based adhesives derived from low-value residues remains elusive. Here, we facilely develop a reused camellia meal-based adhesive integrating excellent mechanical robustness, environment durability, and mildew resistance through the cooperation of dual dynamic bonds. By deliberately harnessing dynamic covalent bonds as the first strong interlinking and dynamic noncovalent bonds as the second weak interaction, our strategy allows the resulting adhesive with a much-improved adhesion strength (2.1/1.06 MPa to wood in dry/wet condition) and remarkable adhesion maintenance against harsh environmental factors (organic solvents, salt, acid, alkali, temperature, soaking time). By virtue of these abundant dynamic bonds, this adhesive not only escapes from the inherent drawback of biomaterials to display enlarged anti-mildew efficacy, but also is capable of reprocessing to gain reusability. Combining these desirous characters with the simple two-step fabrication process, this study provides a great potential for the development of high-performance bio-based adhesives sustainably and intelligently.
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| GB/T 7714 | Zhang, Jiayi , Chen, Nairong , Zhu, Zhiqiang et al. Dual dynamic bonds synergy for reusable bio-based adhesive with superior mechanical robustness, environmental reliability, and mildew resistance [J]. | NPG ASIA MATERIALS , 2025 , 17 (1) . |
| MLA | Zhang, Jiayi et al. "Dual dynamic bonds synergy for reusable bio-based adhesive with superior mechanical robustness, environmental reliability, and mildew resistance" . | NPG ASIA MATERIALS 17 . 1 (2025) . |
| APA | Zhang, Jiayi , Chen, Nairong , Zhu, Zhiqiang , Huang, Youhui , Chen, Lihui , Li, Feng . Dual dynamic bonds synergy for reusable bio-based adhesive with superior mechanical robustness, environmental reliability, and mildew resistance . | NPG ASIA MATERIALS , 2025 , 17 (1) . |
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