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学者姓名：陈奶荣
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Abstract ：
Nickel-cobalt bimetallic sulfides are promising electrode materials for hybrid supercapacitors due to their high theoretical capacity and abundant active sites, but their practical application is limited by poor electrical conductivity and structural instability during cycling. To address these challenges, hierarchical chrysanthemum-shaped Co3S4@Ni3S4@C heterostructures were successfully synthesized via a two-step hydrothermal method using bamboo-derived porous carbon (BNA600). The resulting Co3S4@Ni3S4@C heterostructure exhibited significantly enhanced electrochemical performance, achieving a high specific capacitance of 1016.8 F g-1 at 1 A g-1 in a three-electrode system, along with superior rate capability (80.4 % retention at 10 A g-1). Benefiting from the hierarchical porous morphology, conductive carbon matrix, and optimized electron transport pathways at the heterogeneous interfaces, the assembled hybrid supercapacitor (Co3S4@Ni3S4@C cathode and bamboo-derived porous carbon anode) delivered an ultrahigh energy density of 68.13 Wh kg-1 at a power density of 749.8 W kg-1 and maintained an outstanding energy density of 51.25 Wh kg-1 even at a high power density of 7500 W kg-1, surpassing most previously reported hybrid supercapacitors. Additionally, the device exhibited excellent cycling stability, retaining 89.2 % of initial capacitance after 5000 cycles at 20 A g-1. These results highlight the considerable potential of Co3S4@Ni3S4@C heterostructures derived from bamboo carbon for advanced electrochemical energy storage applications.
Keyword ：
Bamboo-derived porous carbon Bamboo-derived porous carbon Hierarchical heterostructures Hierarchical heterostructures High energy density High energy density Hybrid supercapacitors Hybrid supercapacitors Superior rate capability Superior rate capability
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| GB/T 7714 | Chen, Tong , You, Songyue , Guo, Zhiyun et al. Hierarchical chrysanthemum-shaped Co3S4@Ni3S4@C composites from bamboo-derived carbon with exceptional energy density for hybrid supercapacitors [J]. | JOURNAL OF ENERGY STORAGE , 2025 , 133 . |
| MLA | Chen, Tong et al. "Hierarchical chrysanthemum-shaped Co3S4@Ni3S4@C composites from bamboo-derived carbon with exceptional energy density for hybrid supercapacitors" . | JOURNAL OF ENERGY STORAGE 133 (2025) . |
| APA | Chen, Tong , You, Songyue , Guo, Zhiyun , Zhang, Qianqian , Zheng, Weicheng , Chen, Nairong et al. Hierarchical chrysanthemum-shaped Co3S4@Ni3S4@C composites from bamboo-derived carbon with exceptional energy density for hybrid supercapacitors . | JOURNAL OF ENERGY STORAGE , 2025 , 133 . |
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本发明提供了一种含微凝胶结构的高性能无醛茶籽粕木材胶黏剂及其制备方法。以机械力将茶籽粉碎至粉状，室温下，使用正己烷去除茶籽粕的油脂，进一步粉碎至大于200目，降低其粒径，暴露活性官能团（如氨基、羧基、羟基）。茶籽粕、改性剂和天然多酚在微波控温作用下，发生非共价自组装聚集行为，形成微凝胶，降低体系黏度；后续使用时，在热压过程中，微凝胶破碎，改性剂与茶籽粕中的活性基团反应形成刚性共价网络，含有儿茶酚基团天然多酚与改性剂和茶籽粕形成柔性非共价网络，刚柔并济的交联网络赋予茶籽粕胶黏剂强大的耐水能力，应用前景良好。
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| GB/T 7714 | 陈奶荣 , 吴梓楷 , 黄友辉 et al. 一种含微凝胶结构的高性能无醛茶籽粕木材胶黏剂及其制备方法 : CN202510142848.6[P]. | 2025-02-10 . |
| MLA | 陈奶荣 et al. "一种含微凝胶结构的高性能无醛茶籽粕木材胶黏剂及其制备方法" : CN202510142848.6. | 2025-02-10 . |
| APA | 陈奶荣 , 吴梓楷 , 黄友辉 , 李枫 . 一种含微凝胶结构的高性能无醛茶籽粕木材胶黏剂及其制备方法 : CN202510142848.6. | 2025-02-10 . |
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芳樟醇具有良好的抗菌和抗氧化性，但易挥发且热稳定性差。埃洛石纳米管(HNTs)存在特殊中空孔道结构并具有保护和释放活性物质的功能，常作为纳米载体。因此，开展HNTs负载芳樟醇(LNL)的研究并进行抗菌试验。采用真空负压法将LNL负载到3 mol/L盐酸酸化后的埃洛石纳米管(AC-HNTs)管腔内部，制备出芳樟醇-酸化埃洛石纳米管(L-AC-HNTs)新型防霉抗菌剂。以竹制品中常见的大肠杆菌(Escherichia coli)、金黄色葡萄球菌(Staphylococcus aureus)、黑曲霉菌(Aspergillus niger)、桔青霉菌(Penicillium oryzae)为目标菌种，考察不同添加量L-AC-HNTs的抑菌效果，测试其热稳定性和缓释性并进行表征分析。结果表明：添加1.5%质量浓度的L-AC-HNTs对以上几种细菌和霉菌的抑菌效果最佳，抑菌率均达到了100%。LAC-HNTs的热分解速率峰值温度达到279.9℃，比纯LNL提高了81.5℃，AC-HNTs在50℃下挥发72 h后对LNL的保留率仍为94.6%，仅损失了3.4%，而纯LNL保留率为8%，酸化刻蚀后LNL负载量从5.0%最高提升至15.6%。L-AC-HNTs具有广谱抑菌性和热稳定性，为其在竹制品中的应用提供参考。
Keyword ：
埃洛石纳米管 埃洛石纳米管 热稳定性 热稳定性 芳樟醇 芳樟醇 负载 负载 防霉抗菌 防霉抗菌
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| GB/T 7714 | 张原菘 , 甘雯馨 , 曾钦志 et al. 埃洛石纳米管负载芳樟醇及其防霉抗菌性能 [J]. | 复合材料学报 , 2025 , 42 (05) : 2854-2865 . |
| MLA | 张原菘 et al. "埃洛石纳米管负载芳樟醇及其防霉抗菌性能" . | 复合材料学报 42 . 05 (2025) : 2854-2865 . |
| APA | 张原菘 , 甘雯馨 , 曾钦志 , 赵伟刚 , 陈奶荣 , 饶久平 . 埃洛石纳米管负载芳樟醇及其防霉抗菌性能 . | 复合材料学报 , 2025 , 42 (05) , 2854-2865 . |
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本发明提供了一种全组分利用虾蟹壳制备木材胶黏剂的方法，以废弃虾蟹壳为原料，经过球磨、表面氨基化等步骤，解聚组分，再固化交联，制备成胶黏剂；该方法不仅充分利用渔业加工废弃物，还提高了胶黏剂的耐水粘接性能。该胶黏剂可用于生产刨花板、纤维板、胶合板等人造板，制备的人造板无游离甲醛释放，具有天然的抗菌防霉效果，能够广泛用于家具或装修行业，具有广阔的应用前景。
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| GB/T 7714 | 陈奶荣 , 朱志强 , 李枫 . 一种全组分利用虾蟹壳制备木材胶黏剂的方法 : CN202410295577.3[P]. | 2024-03-15 . |
| MLA | 陈奶荣 et al. "一种全组分利用虾蟹壳制备木材胶黏剂的方法" : CN202410295577.3. | 2024-03-15 . |
| APA | 陈奶荣 , 朱志强 , 李枫 . 一种全组分利用虾蟹壳制备木材胶黏剂的方法 : CN202410295577.3. | 2024-03-15 . |
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本发明公开了一种基于仿生矿化有机‑无机杂化的水下胶黏剂及其制备方法和应用，属于胶黏剂技术领域。所述胶黏剂包括不饱和油脂、无机化合物及氧化剂。本发明的胶黏剂对于各种基材均具有高的胶接强度，并且在各种溶液环境中保持较高强度。本发明的胶黏剂可用于水下结构的胶接、维修和加固。本发明选用的原料价廉易得，制备工艺简单，无需复杂合成，适合工业规模化生产，在胶黏剂技术领域具有深远的应用前景。
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| GB/T 7714 | 李枫 , 李梦涵 , 陈奶荣 et al. 一种基于仿生矿化有机-无机杂化的水下胶黏剂及其制备方法和应用 : CN202510389993.4[P]. | 2025-03-31 . |
| MLA | 李枫 et al. "一种基于仿生矿化有机-无机杂化的水下胶黏剂及其制备方法和应用" : CN202510389993.4. | 2025-03-31 . |
| APA | 李枫 , 李梦涵 , 陈奶荣 , 朱志强 , 黄友辉 , 张嘉怡 . 一种基于仿生矿化有机-无机杂化的水下胶黏剂及其制备方法和应用 : CN202510389993.4. | 2025-03-31 . |
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Introducing dynamics into bio-based adhesives shows many advantages on rendering mechanics and functions. However, the efficient employment of dynamic chemistry in achieving robust, stable, and reusable bio-based adhesives derived from low-value residues remains elusive. Here, we facilely develop a reused camellia meal-based adhesive integrating excellent mechanical robustness, environment durability, and mildew resistance through the cooperation of dual dynamic bonds. By deliberately harnessing dynamic covalent bonds as the first strong interlinking and dynamic noncovalent bonds as the second weak interaction, our strategy allows the resulting adhesive with a much-improved adhesion strength (2.1/1.06 MPa to wood in dry/wet condition) and remarkable adhesion maintenance against harsh environmental factors (organic solvents, salt, acid, alkali, temperature, soaking time). By virtue of these abundant dynamic bonds, this adhesive not only escapes from the inherent drawback of biomaterials to display enlarged anti-mildew efficacy, but also is capable of reprocessing to gain reusability. Combining these desirous characters with the simple two-step fabrication process, this study provides a great potential for the development of high-performance bio-based adhesives sustainably and intelligently.
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| GB/T 7714 | Zhang, Jiayi , Chen, Nairong , Zhu, Zhiqiang et al. Dual dynamic bonds synergy for reusable bio-based adhesive with superior mechanical robustness, environmental reliability, and mildew resistance [J]. | NPG ASIA MATERIALS , 2025 , 17 (1) . |
| MLA | Zhang, Jiayi et al. "Dual dynamic bonds synergy for reusable bio-based adhesive with superior mechanical robustness, environmental reliability, and mildew resistance" . | NPG ASIA MATERIALS 17 . 1 (2025) . |
| APA | Zhang, Jiayi , Chen, Nairong , Zhu, Zhiqiang , Huang, Youhui , Chen, Lihui , Li, Feng . Dual dynamic bonds synergy for reusable bio-based adhesive with superior mechanical robustness, environmental reliability, and mildew resistance . | NPG ASIA MATERIALS , 2025 , 17 (1) . |
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本发明提供了一种解聚虾蟹壳改性的低游离甲醛氨基树脂胶黏剂及其制备方法。以机械力将甲壳类动物外壳粉碎成粉状，降低其粒径，形成微米尺度虾蟹壳微粒，提高比表面积。分别以酸和碱依次溶解虾蟹壳粉中的部分碳酸钙和蛋白质，虾蟹壳微粒表面将暴露出大量甲壳素。以碱液溶解蛋白质，也会引发甲壳素脱乙酰基，产生‑NH2等官能团。这样，微粒表面将生成大量含氨基的壳聚糖。氨基与脲醛树脂中的游离甲醛/羟甲基反应，既对树脂起增强作用，又降低了游离甲醛含量。
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| GB/T 7714 | 陈奶荣 , 朱志强 , 李枫 . 一种解聚虾蟹壳改性的低游离甲醛氨基树脂胶黏剂及其制备方法 : CN202410295620.6[P]. | 2024-03-15 . |
| MLA | 陈奶荣 et al. "一种解聚虾蟹壳改性的低游离甲醛氨基树脂胶黏剂及其制备方法" : CN202410295620.6. | 2024-03-15 . |
| APA | 陈奶荣 , 朱志强 , 李枫 . 一种解聚虾蟹壳改性的低游离甲醛氨基树脂胶黏剂及其制备方法 : CN202410295620.6. | 2024-03-15 . |
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脲醛树脂（UF）在生产和使用过程中具有释放游离甲醛的缺点，以低摩尔比（F/U）生产UF是降低游离甲醛的有效手段，但会对其胶合强度产生负面影响。本研究采用聚二苯基甲烷二异氰酸酯（pMDI）改性低游离甲醛含量UF，再检测其相关性能。结果表明：随着pMDI用量的增加，UF黏度上升、固化时间下降、不溶物含量增加。当pMDI的添加量为9%时，胶合强度提升幅度最大，干状胶合强度为1.17 MPa，湿状胶合强度为1.15 MPa。当pMDI的添加量为5%时，湿状胶合强度为0.76 MPa，达到GB/T 9846—2015《普通胶合板》中室内Ⅱ类胶合板的要求。同时，固化的UF形成氨基甲酸酯结构，表现出更好的耐热性。
Keyword ：
异氰酸酯 异氰酸酯 木材胶黏剂 木材胶黏剂 甲醛 甲醛 胶合板 胶合板 脲素 脲素
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| GB/T 7714 | 黄友辉 , 吴梓楷 , 朱志强 et al. 异氰酸酯改性脲醛树脂胶黏剂的性能研究 [J]. | 林产工业 , 2025 , 62 (01) : 1-6 . |
| MLA | 黄友辉 et al. "异氰酸酯改性脲醛树脂胶黏剂的性能研究" . | 林产工业 62 . 01 (2025) : 1-6 . |
| APA | 黄友辉 , 吴梓楷 , 朱志强 , 林志伟 , 叶世俊 , 陈奶荣 . 异氰酸酯改性脲醛树脂胶黏剂的性能研究 . | 林产工业 , 2025 , 62 (01) , 1-6 . |
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Composite materials, particularly wood-based panels, are frequently subjected to the harsh conditions of their service environments, leading to adhesive layer degradation and a consequent reduction in mechanical integrity and service life. The integration of self-repairing capabilities into these composites via microencapsulation presents a promising strategy to mitigate such degradation. Here, we developed a unique soy-protein-based adhesive with self-repairing capability by leveraging Pickering emulsion templated microcapsules. The microcapsules possess a melamine formaldehyde resin/polyurea shell and an isophorone diisocyanate (IPDI) core, which can exhibit excellent stability to maintain a 60.6 % encapsulation efficiency even after storing for 30 days. By incorporating with the microcapsules, the adhesive is demonstrated to display pressure-sensitive behavior. Such behavior enables the release of IPDI through mechanical stress and thus crosslinks with soy protein for crack repairing. The feature of wide particle size distribution of the microcapsules contributes to enhance both adhesion strength (reaching to 0.82 MPa to wood) and self-repairing rate (up to 93.5 %) of the wood-based composite. This innovative approach offers a practical and efficient method for endowing wood-based panels with autonomous healing capabilities, paving the way for the development of advanced self-repairing biomass composites. © 2025
Keyword ：
Adhesives Adhesives Biomass Biomass Crosslinking Crosslinking Emulsification Emulsification Emulsions Emulsions Energy efficiency Energy efficiency Hydroelasticity Hydroelasticity Microencapsulation Microencapsulation Ostwald ripening Ostwald ripening Wood products Wood products
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| GB/T 7714 | Huang, Youhui , Tu, Yijing , Zhu, Zhiqiang et al. Self-repairing wood-based composites enabled by pressure-sensitive soy-protein-based adhesive containing microcapsules [J]. | Results in Engineering , 2025 , 25 . |
| MLA | Huang, Youhui et al. "Self-repairing wood-based composites enabled by pressure-sensitive soy-protein-based adhesive containing microcapsules" . | Results in Engineering 25 (2025) . |
| APA | Huang, Youhui , Tu, Yijing , Zhu, Zhiqiang , Zhang, Jiayi , Li, Feng , Chen, Nairong . Self-repairing wood-based composites enabled by pressure-sensitive soy-protein-based adhesive containing microcapsules . | Results in Engineering , 2025 , 25 . |
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Biomass-derived materials have garnered significant attention as sustainable anode candidates for lithium-ion batteries (LIBs) owing to their abundance, low cost, and environmental benefits. Among these, Cenchrus fungigraminus (JUJUNCAO) stands out due to its rapid growth, high yield, and exceptional environmental adaptability, making it a promising precursor for carbon-based electrodes. In this study, activated carbon was synthesized from JUJUNCAO through a two-step process involving carbonization and KOH activation. By systematically varying the activation temperature and the biochar/KOH weight ratio, we precisely controlled key properties such as the degree of graphitization, porosity, chemical composition, and electrochemical performance. The optimized activated carbon exhibited a high specific surface area of 1055 m2 g- 1 and delivered a reversible specific capacity of 393 mAh g- 1 after 650 charge/discharge cycles at a current density of 0.1 A g- 1. This superior electrochemical performance is attributed to the hierarchical porous structure and heteroatom doping, which synergistically enhance lithium-ion diffusion and electron transport. These findings not only underscore the potential of JUJUNCAO as a sustainable, high-performance anode material for LIBs but also pave the way for the high-value utilization of biomass in green energy storage technologies.
Keyword ：
Activated carbon Activated carbon Carbonization temperature Carbonization temperature JUJUNCAO (Cenchrus fungigraminus) JUJUNCAO (Cenchrus fungigraminus) KOH activation KOH activation Lithium-ion battery Lithium-ion battery
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| GB/T 7714 | Guo, Zhiyun , Cheng, Tong , Zheng, Weicheng et al. Sustainable anode materials from Cenchrus fungigraminus biomass for advanced lithium-ion batteries [J]. | JOURNAL OF ELECTROANALYTICAL CHEMISTRY , 2025 , 985 . |
| MLA | Guo, Zhiyun et al. "Sustainable anode materials from Cenchrus fungigraminus biomass for advanced lithium-ion batteries" . | JOURNAL OF ELECTROANALYTICAL CHEMISTRY 985 (2025) . |
| APA | Guo, Zhiyun , Cheng, Tong , Zheng, Weicheng , Zeng, Qinzhi , Chen, Nairong , Zhao, Weigang et al. Sustainable anode materials from Cenchrus fungigraminus biomass for advanced lithium-ion batteries . | JOURNAL OF ELECTROANALYTICAL CHEMISTRY , 2025 , 985 . |
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