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学者姓名：陈孝云
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Abstract ：
To address the limitations of conventional powdered catalytic materials, including difficulty of recycling, low catalytic activity, and limited applicability to different pollutants, this study developed a wood-based@InCoOS composite catalytic materials with rapid recycling characteristics and suitable for the catalytic reduction of various pollutants. By employing bimetallic oxysulfide in situ decoration, the wood was successfully endowed with catalytic functionality, and the catalytic activities of poplar wood-based (PT@InCoOS) and Chinese fir wood-based (CF@InCoOS) composite catalytic materials were compared across multiple pollutants. The results revealed that both PT@InCoOS and CF@InCoOS showed excellent catalytic reduction performance, but with significant differences. PT@InCoOS achieved complete reduction of new coccine (NC), methylene blue (MB), and rhodamine B (RhB) within 3, 3, and 20 min, respectively, and completely reduced Cr(VI) and p-nitrophenol (4NP) within 22 and 20 min. In contrast, CF@InCoOS required 5, 4, 24, 32, and 30 min for the same pollutants. PT@InCoOS exhibited superior performance due to its higher electron transferring capability and favorable bandgap structure, while the interfacial synergistic effect effectively promoted the photogenerated carrier transport and utilization efficiency. Even after six cycles of use, wood-based@InCoOS composite catalytic materials retained over 88 % of their catalytic efficiency, demonstrating excellent reusability. The materials have low cost, high activity, easy recycling, and environmental friendliness and demonstrate great potential as a microreactor in environmental remediation.
Keyword ：
Bimetallic oxysulfide Bimetallic oxysulfide Catalytic reduction Catalytic reduction Cr (VI) and 4-NP Cr (VI) and 4-NP Organic dyes Organic dyes Recyclable materials Recyclable materials Wastewater treatment Wastewater treatment Wood-based functional materials Wood-based functional materials
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| GB/T 7714 | Bao, Xinde , Yang, Meng , Hong, Yuhao et al. Rapid recyclable wood-based@InCoOS composite catalytic materials: Achieving efficient catalytic reduction and recycling of multiple pollutants [J]. | SEPARATION AND PURIFICATION TECHNOLOGY , 2026 , 380 . |
| MLA | Bao, Xinde et al. "Rapid recyclable wood-based@InCoOS composite catalytic materials: Achieving efficient catalytic reduction and recycling of multiple pollutants" . | SEPARATION AND PURIFICATION TECHNOLOGY 380 (2026) . |
| APA | Bao, Xinde , Yang, Meng , Hong, Yuhao , Guan, Xin , Chen, Xiaoyun , Lin, Jinguo . Rapid recyclable wood-based@InCoOS composite catalytic materials: Achieving efficient catalytic reduction and recycling of multiple pollutants . | SEPARATION AND PURIFICATION TECHNOLOGY , 2026 , 380 . |
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To reveal the role of bi-vacancy defects and heterovalent states in oxysulfide catalysts for enhancing the photocatalytic hydrogen evolution reaction (PHER), we demonstrate a Br/W co-doped Zn(O,S) catalyst (labeled as Br/W-ZnOS) featuring abundant anionic oxygen vacancies (VO)/cationic zinc vacancies (VZn) bi-defects and heterovalent W5+/W6+ states via a facile hydrolysis method. The co-doping of Br and W induces lattice distortions that enable neighboring atoms to leave the lattice, creating surfaces enriched with anionic VO and cationic VZn defects. The synergistic effect between dual defects forms an efficient electron-hole separation system, enhancing the efficiency of electron-hole pair separation. Density functional theory calculation (DFT) demonstrates that the combination of Br/W co-doping and vacancies significantly reduces the water dissociation barrier and optimizes the surface *H generation rate of the photocatalyst. Thus, Br/W-ZnOS exhibits a PHER rate of 3415.7 mu mol h- 1, which is 12.5 times higher than the undoped Zn(O,S) catalyst, and achieves an apparent quantum yield (AQY) of 15.41 % at 365 nm, while maintaining good stability with a PHER activity of 3288.1 mu mol h- 1 after five repeated cycles. This research provides a promising strategy for designing oxysulfide catalysts with synergistically engineered defects for efficient PHER.
Keyword ：
Heterovalent states Heterovalent states Photocatalytic hydrogen evolution Photocatalytic hydrogen evolution W/Br co-doped W/Br co-doped Zn/O bi-vacancy defects Zn/O bi-vacancy defects
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| GB/T 7714 | Wu, Binghong , Wu, Xinru , Kuo, Dong-Hau et al. W/Br co-doped Zn(O,S) with Zn/O bi-vacancy defects and heterovalent states for enhanced photocatalytic hydrogen evolution [J]. | MATERIALS TODAY ENERGY , 2025 , 49 . |
| MLA | Wu, Binghong et al. "W/Br co-doped Zn(O,S) with Zn/O bi-vacancy defects and heterovalent states for enhanced photocatalytic hydrogen evolution" . | MATERIALS TODAY ENERGY 49 (2025) . |
| APA | Wu, Binghong , Wu, Xinru , Kuo, Dong-Hau , Tang, Xiao , Mao, Xin , Yang, Baoqian et al. W/Br co-doped Zn(O,S) with Zn/O bi-vacancy defects and heterovalent states for enhanced photocatalytic hydrogen evolution . | MATERIALS TODAY ENERGY , 2025 , 49 . |
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Environment and energy are presently some of the highest priority topics for mankind that need to be addressed. Organic pollutants are toxic and carcinogenic for human and aquatic life hence their presence in water even in low concentrations can cause serious health problems. Photodegradation of organic pollutants by utilizing oxidebased heterostructure photocatalysts is the promising approach to carry out remediation efficiently ascribed to the advanced optoelectronic and structural superiority of oxide photocatalysts. The Zn(O,S)/Mo(O,S)2 composites were synthesized via a facile solvothermal method at low temperatures. Several methods were used to characterize the composite morphology, structure, electrical conductivity, chemical composition, and optical characteristics. The heterostructured Zn(O,S)/Mo(O,S)2 oxysulfide was employed successfully in the photocatalytic degradation of organic pollutants. Among the as-prepared samples, the 30-ZnMoOS composite catalyst was found to have the highest photodegradation performance on various organic dye pollutants. The photocatalytic activity of the as-synthesized Zn(O,S)/Mo(O,S)2 samples was assessed on the photodegradation of different kinds of organic dyes under visible light irradiation. The photocatalytic degradation efficiency of 30ZnMoOS composite over 10 ppm neutral red (NR), methylene blue (MB), rhodamine B (Rh B), and methyl orange (MO) was found to be 99.6%, 99.9%, 99.5%, and 98.8% within 40, 45, 180, and 180 min, respectively, under visible light illumination. In the present photocatalytic system, the superoxide ( . O 2- ) anions, hydroxyl (.OH) radicals, and holes (h+) are proposed to be the direct reactive species causing the photodegradation of organic dyes.
Keyword ：
30-ZnMoOS 30-ZnMoOS Composite Composite Degradation Degradation Organic pollutants Organic pollutants Photocatalyst Photocatalyst Visible light Visible light
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| GB/T 7714 | Kebede, Worku Lakew , Kuo, Dong-Hau , Chen, Xiaoyun . Highly efficient Zn(O,S)/Mo(O,S)2 oxysulfide heterostructure photocatalyst for organic pollutant degradation [J]. | COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS , 2025 , 705 . |
| MLA | Kebede, Worku Lakew et al. "Highly efficient Zn(O,S)/Mo(O,S)2 oxysulfide heterostructure photocatalyst for organic pollutant degradation" . | COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS 705 (2025) . |
| APA | Kebede, Worku Lakew , Kuo, Dong-Hau , Chen, Xiaoyun . Highly efficient Zn(O,S)/Mo(O,S)2 oxysulfide heterostructure photocatalyst for organic pollutant degradation . | COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS , 2025 , 705 . |
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A novel AgVOS oxysulfide catalyst for rapid catalytic reduction of toxic organic substances and Cr(VI) under dark is synthesized by a facile method. With the V/O co-doping, the doped Ag2S catalyst has the effectively regulated electron transfer performance, the hydrazine-driven V5+-to-V4+ reduction to disturb charge equilibrium, and the formed sulfur vacancy balanced by oxygen doping to maintain charge equilibrium. The formed sulfur vacancy acts as the active site for electrophilic nucleophilic reaction, while the orbital hybridization of O-2p and S-3p stabilizes the valence state of S2-. A suitable ratio of n(V4+/V5+) is regulated during the hydrazine-driven synthesis to facilitate the electron transfer and enhance the V5+-to-V4+ reduction reaction. V/O co-doped AgVOS-3 prepared by a suitable hydrazine content exhibits super catalytic reduction performance of organic 4-NP (4-nitrophenol), MB (methyl blue), MO (methyl orange), and RhB (Rhodamine B, 20 ppm, 100 mL) dyes, which are completely reduced within 8, 8, 10, and 8 min, respectively. In comparison, Cr6+ (50 ppm, 100 mL) is also completely reduced within 6 min by AgVOS-3, indicating its good catalytic reduction activity for organic and inorganic mixture pollutants. Furthermore, AgVOS-3 has good stability after cyclic tests to maintain a reduction efficiency of 96.5%. Therefore, the AgVOS catalyst shows a promising application for industrial wastewater treatment.
Keyword ：
bimetal oxysulfide bimetal oxysulfide heterovalent states heterovalent states pollutant reduction pollutant reduction sulfur vacancy sulfur vacancy V/O co-doped Ag2S V/O co-doped Ag2S
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| GB/T 7714 | Wu, Xinru , Zhang, Pengkun , Insua, Benjamin Kunkadma et al. V-/O-Doping to Endow Ag2S-based Bimetal Oxysulfide with Sulfur Vacancies and Heterovalent States for Rapid Reduction of Organic and Cr(VI) Pollutants in the Dark [J]. | ADVANCED SUSTAINABLE SYSTEMS , 2025 , 9 (3) . |
| MLA | Wu, Xinru et al. "V-/O-Doping to Endow Ag2S-based Bimetal Oxysulfide with Sulfur Vacancies and Heterovalent States for Rapid Reduction of Organic and Cr(VI) Pollutants in the Dark" . | ADVANCED SUSTAINABLE SYSTEMS 9 . 3 (2025) . |
| APA | Wu, Xinru , Zhang, Pengkun , Insua, Benjamin Kunkadma , Yang, Baoqian , Kuo, Dong-Hau , Lu, Dongfang et al. V-/O-Doping to Endow Ag2S-based Bimetal Oxysulfide with Sulfur Vacancies and Heterovalent States for Rapid Reduction of Organic and Cr(VI) Pollutants in the Dark . | ADVANCED SUSTAINABLE SYSTEMS , 2025 , 9 (3) . |
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While bismuth oxychloride is a known photocatalyst, its single-phase form for photocatalytic hydrogen evolution (PHER) has rarely been explored. This paper presents a novel approach to the 'braided-channel' structured and superhydrophilic Mn/S co-doped BiOCl-based bimetal sulfur-oxychloride catalyst (Mn/S-BiOCl). With its enriched oxygen-vacancy defect and heterovalent states, this catalyst demonstrates efficient PHER under visible light. The Mn/S co-doping in BiOCl adjusts the band structure and expands the visible light response range, a unique strategy for forming photocatalysts for hydrogen evolution and transforming hydrophobicity into superhydrophilicity. The introduction of sulfur regulates the oxygen-vacancy contents to enhance water molecule trapping on active sites and activating H-O-H bonds. Our density functional theory (DFT) calculation reveals that Mn/S co-doped BiOCl with oxygen vacancy (Vo) defects weakens the H-O-H bond and reduces the reaction adsorption energy of H2O, resulting in high selectivity. In addition, heterovalent Mn2+/Mn3+ and Bi3+/Bi5+ are conducive to the accelerated electron jump, extended electron lifetime, and elevated PHER activity. The Mn/SBiOCl-3 prepared with a suitable Mn/S co-doping content exhibited the highest PHER rate of 607.5 mu mol & sdot;h-1 under visible light, with an apparent quantum efficiency (AQE) of 11.6 % at 420 nm. This successful design in Mn/S-BiOCl with excellent PHER activity, stability, and durability provides a novel and feasible idea and scheme for applying bismuth-based halide oxides in PHER.
Keyword ：
Mn/S co-doped BiOCl Mn/S co-doped BiOCl Oxygen vacancies Oxygen vacancies Photocatalytic hydrogen evolution Photocatalytic hydrogen evolution Sulfur-oxychloride catalyst Sulfur-oxychloride catalyst Superhydrophilic Superhydrophilic
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| GB/T 7714 | Su, Zhengjie , Wu, Binghong , Li, Cuizhu et al. Mn/S co-doped BiOCl regulated with a hydrophobic-to-superhydrophilic transition and oxygen-vacancy defects for assisting photocatalytic hydrogen evolution [J]. | CHEMICAL ENGINEERING JOURNAL , 2025 , 510 . |
| MLA | Su, Zhengjie et al. "Mn/S co-doped BiOCl regulated with a hydrophobic-to-superhydrophilic transition and oxygen-vacancy defects for assisting photocatalytic hydrogen evolution" . | CHEMICAL ENGINEERING JOURNAL 510 (2025) . |
| APA | Su, Zhengjie , Wu, Binghong , Li, Cuizhu , Kuo, Dong-Hau , Zhang, Pengkun , Chen, Longyan et al. Mn/S co-doped BiOCl regulated with a hydrophobic-to-superhydrophilic transition and oxygen-vacancy defects for assisting photocatalytic hydrogen evolution . | CHEMICAL ENGINEERING JOURNAL , 2025 , 510 . |
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The efficient removal of lignin is crucial for process optimization, as it enhances the exposure of polar groups in wood and provides interfacial binding sites for subsequent material modifications. In this study, an environmentally friendly peracetic acid/ hydrogen peroxide system was employed to delignify fast-growing wood. The results indicated mass loss rates of 30.7% for poplar and 31.3% for Chinese fir, with corresponding decreases in relative lignin content by 95.3% and 87.2%, respectively. Additionally, the specific surface area increased by 6.4% in poplar and 30.9% in Chinese fir. The relative crystallinity was enhanced by 31.2% in poplar and 15.7% in Chinese fir, and the O/C ratio increased by 29.6% and 19.7%, respectively. Microsocopic morphological analysis revealed noticeably thinner and slightly collapsed cell walls in the treated samples. The disappearance of lignin-specific peaks at 1507 cm-1, 1460 cm-1, and 1264 cm-1 confirmed the effective removal of lignin. Additionally, delignification resulted in a lower pyrolysis temperature, increased surface brightness, and reduced color variation. Due to the differences in internal structures and chemical compositions between poplar and Chinese fir, the effects of lignin removal varied, leading to significant changes in their physicochemical properties. These findings provide a theoretical foundational for lignin removal from wood and support future efforts in wood functionalization.
Keyword ：
Chinese fir wood Chinese fir wood Delignification treatment Delignification treatment Fast growing wood Fast growing wood Lignin Lignin Poplar wood Poplar wood
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| GB/T 7714 | Bao, Xinde , Yang, Meng , Zhu, Junjie et al. Efficient delignification of poplar and Chinese fir wood using a peroxyacetic acid/hydrogen peroxide system [J]. | JOURNAL OF WOOD SCIENCE , 2025 , 71 (1) . |
| MLA | Bao, Xinde et al. "Efficient delignification of poplar and Chinese fir wood using a peroxyacetic acid/hydrogen peroxide system" . | JOURNAL OF WOOD SCIENCE 71 . 1 (2025) . |
| APA | Bao, Xinde , Yang, Meng , Zhu, Junjie , Xu, Hui , Dang, Huiying , Guo, Kai et al. Efficient delignification of poplar and Chinese fir wood using a peroxyacetic acid/hydrogen peroxide system . | JOURNAL OF WOOD SCIENCE , 2025 , 71 (1) . |
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The functional moieties and three-dimensional molecular structure make lignin a suitable active catalyst support, thereby controlling the size, enhancing stability, overcoming aggregation through a uniform distribution, and allowing catalyst reusability. In this study, Ag-/Mo-doped Ce4O4S3 oxysulfide supported on lignin (Ln) prepared from black lignin liquor at different pH mediums was synthesized by a facile approach and examined for photocatalytic hydrogen evolution reaction (PHER) and 4-Nitrophenol (4-NP) reduction. The Ag-/Mo-doped Ce4O4S3 supported on lignin prepared at pH = 6.5 (Ag-/Mo-doped Ce4O4S3@Ln-1) showed excellent stability and catalytic activity for the PHER at 516.24 mu mol/h H2 with 30 mg catalyst and achieved apparent quantum efficiency (AQE) of 17.46 % at lambda = 420 nm, and 91.4 % of the 4-NP reduction within 135 min by in-situ generated protons and electrons. In the presence of 4-NP, the in situ-generated protons and electrons executed the reduction of 4-NP rather than preceding H2 evolution. Lignin contributes to the Ag-/Mo-doped Ce4O4S3@Ln having a high specific surface area. The porous lignin structure and functional groups act as active sites for the adsorption of H2O and 4-NP molecules, thereby enhancing reaction kinetics and improving photocatalytic performance of Ag-/Mo-doped Ce4O4S3@Ln. So, the lignin-mediated catalyst synthesis route is a promising approach for designing novel, efficient, and stable metallic catalysts.
Keyword ：
4-NP reduction 4-NP reduction H 2 evolution H 2 evolution Lignin Lignin
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| GB/T 7714 | Abdeta, Adugna Boke , Tilachew, Gemechis , Wedajo, Feyisa et al. Lignin-supported Ag-/Mo-doped Ce4O4S3 oxysulfide catalyst for visible-light-driven water-splitting as a green way of H2 evolution and 4-nitrophenol reduction [J]. | JOURNAL OF WATER PROCESS ENGINEERING , 2025 , 79 . |
| MLA | Abdeta, Adugna Boke et al. "Lignin-supported Ag-/Mo-doped Ce4O4S3 oxysulfide catalyst for visible-light-driven water-splitting as a green way of H2 evolution and 4-nitrophenol reduction" . | JOURNAL OF WATER PROCESS ENGINEERING 79 (2025) . |
| APA | Abdeta, Adugna Boke , Tilachew, Gemechis , Wedajo, Feyisa , Ayana, Kitesa , Mubiayi, Pierre Kalenga , Banda, Maria et al. Lignin-supported Ag-/Mo-doped Ce4O4S3 oxysulfide catalyst for visible-light-driven water-splitting as a green way of H2 evolution and 4-nitrophenol reduction . | JOURNAL OF WATER PROCESS ENGINEERING , 2025 , 79 . |
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NH
Keyword ：
Zn Zn
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| GB/T 7714 | 张鹏坤 , 吴秦汉 , 王昊昱 et al. Z型异质结Zn [J]. | Chinese Journal of Catalysis , 2025 , 74 (07) : 279-293 . |
| MLA | 张鹏坤 et al. "Z型异质结Zn" . | Chinese Journal of Catalysis 74 . 07 (2025) : 279-293 . |
| APA | 张鹏坤 , 吴秦汉 , 王昊昱 , 郭东昊 , 赖雨洁 , 陆东芳 et al. Z型异质结Zn . | Chinese Journal of Catalysis , 2025 , 74 (07) , 279-293 . |
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Lignin, a negatively charged, three-dimensional natural biopolymer, serves as an ideal support for metal catalysts due to its abundant functional groups and tunable chemical properties, which enable strong metal coordination and effective immobilization. Herein, we demonstrate a lignin-mediated Co/O co-doped Ag2S, symbolized as LAgCoOS, bimetal oxysulfide catalyst via a facile hydrolysis method for the efficient reduction of toxic phenolic compounds (4-nitrophenol, 4-NP), organic dyes (methyl orange (MO), methylene blue (MB), rhodamine B (RhB), and heavy metal ions Cr(VI)) under dark conditions. Lignin, used to immobilize catalysts, also contributes to increasing the number of active catalytic sites and enhancing catalytic activity. The co-doping of transition metal cations and anions was employed to effectively regulate the electron transfer property of the catalyst, with oxygen doping modifying the energy band structure and cobalt providing heterovalent Co3+/Co2+ states that facilitate rapid electron hopping between Co2+ and Co3+ (Co2+ <-> Co3+) to transfer for catalytic reduction of pollutants. Furthermore, the hybridization of O 2p and S 3p orbitals improved the structural stability of the catalyst. L-AgCoOS with an appropriate level of cobalt doping exhibited significantly enhanced catalytic reduction efficiency. Specifically, 5 mg of L-AgCoOS-2 could completely reduce 100 ml of 20 ppm 4-NP within 8 min, with the reaction rate constant of 0.26 min-1. Additionally, it achieved a complete reduction of 100 ml of 50 ppm MB, MO, RhB, and Cr(VI) in 4, 3, 4, and 4 min, respectively, with the reaction rate constant of 0.49, 0.51, 0.57, and 0.54 min-1. L-AgCoOS-2 also demonstrated excellent performance in treating mixed pollutants, maintaining high activity across a wide pH range, and good reusability. These results highlight the significant potential of L-AgCoOS-2 for practical applications in wastewater treatment.
Keyword ：
Bimetal oxysulfide catalyst Bimetal oxysulfide catalyst Lignin Lignin Pollutants reduction Pollutants reduction Under dark Under dark
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| GB/T 7714 | Liu, Tao , Wu, Zhenjie , Liu, Yang et al. Lignin-mediated AgCoOS bimetal oxysulfide catalysts for highly efficient catalytic reduction of organic and Cr(VI) pollutants in the dark [J]. | INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES , 2025 , 328 . |
| MLA | Liu, Tao et al. "Lignin-mediated AgCoOS bimetal oxysulfide catalysts for highly efficient catalytic reduction of organic and Cr(VI) pollutants in the dark" . | INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES 328 (2025) . |
| APA | Liu, Tao , Wu, Zhenjie , Liu, Yang , Xiang, Kening , Wang, Haoyu , Li, Cuizhu et al. Lignin-mediated AgCoOS bimetal oxysulfide catalysts for highly efficient catalytic reduction of organic and Cr(VI) pollutants in the dark . | INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES , 2025 , 328 . |
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A Co/O co-doped ZnS-based bimetal oxysulfide (labeled as ZnCoOS) with heterovalent Co2+/Co3+ states and rich sulfur vacancies (Vs) defects was designed via a facile method for photocatalytic hydrogen evolution reaction (PHER). ZnCoOS possesses excellent electrical conductivity and electron trapping capacity, providing more reactive active sites. Introducing Co-/O- to regulate ZnCoOS with abundant Vs defects acts as active sites to trap H2O molecules and activate H-O-H bonds, producing protons for H2 production. Hydrogen peroxide regulated ZnCoOS, offering suitable heterovalent Co2+/Co3+ states and providing sites for photogenerated electrons to rapidly hop between Co2+ and Co3+ for charge transfer during PHER. The ZnCoOS-3 with optimal hydrogen peroxide regulation achieved an excellent PHER rate of 2180 mu mol h- 1 and AQE of 19.11% at 365 nm, approximately 8 times higher than monometallic ZnOS and 5.5 times higher than ZnCoOS prepared without H2O2. Furthermore, ZnCoOS had good photocatalytic stability and durability. A rational mechanism to enhance PHER activity was also explored, providing new insights into the design and application of ZnCoOS bimetal oxysulfide for PHER.
Keyword ：
Bimetal oxysulfide Bimetal oxysulfide Co/O co-doped ZnS Co/O co-doped ZnS Heterovalent states Heterovalent states Photocatalytic hydrogen evolution Photocatalytic hydrogen evolution Sulfur vacancy defects Sulfur vacancy defects
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| GB/T 7714 | Chen, Longyan , Wu, Binghong , Wu, Xinru et al. Synergistic engineering of heterovalent states and sulfur-vacancy defects in Co/O co-doped ZnS for enhanced photocatalytic hydrogen evolution [J]. | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY , 2025 , 98 : 944-956 . |
| MLA | Chen, Longyan et al. "Synergistic engineering of heterovalent states and sulfur-vacancy defects in Co/O co-doped ZnS for enhanced photocatalytic hydrogen evolution" . | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 98 (2025) : 944-956 . |
| APA | Chen, Longyan , Wu, Binghong , Wu, Xinru , Kuo, Dong-Hau , Wan, Tsz Lok , Yang, Baoqian et al. Synergistic engineering of heterovalent states and sulfur-vacancy defects in Co/O co-doped ZnS for enhanced photocatalytic hydrogen evolution . | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY , 2025 , 98 , 944-956 . |
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